2,6-Dibromoanthraquinone

Base Information

• Chemical Name: 2,6-Dibromoanthraquinone
• CAS No.: 633-70-5
• Molecular Formula: C14H6Br2O2
• Molecular Weight: 366.008
• Hs Code.: 2914700090
• DSSTox Substance ID: DTXSID00449859
• Nikkaji Number: J95.572H
• Wikidata: Q72463803
• Mol file: 633-70-5.mol

Synonyms:2,6-Dibromoanthraquinone;633-70-5;2,6-dibromoanthracene-9,10-dione;C14H6Br2O2;9,10-Anthracenedione, 2,6-dibromo-;MFCD08276344;2,6-dibromanthrachinon;2,6-dibromo-9,10-dihydroanthracene-9,10-dione;SCHEMBL762135;AMY434;DTXSID00449859;JUFYHUWBLXKCJM-UHFFFAOYSA-N;2,6-Dibromo-9,10-anthraquinone;BCP05170;AKOS015835858;CS-W008111;SB66745;AC-24443;AS-19011;SY030650;D3182;FT-0655506;A834349;J-507405

Chemical Property of 2,6-Dibromoanthraquinone

Chemical Property:

• Appearance/Colour: Light yellow crystal powder
• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 290 °C
• Refractive Index: 1.701
• Boiling Point: 491.797 °C at 760 mmHg
• Flash Point: 172.19 °C
• PSA: 34.14000
• Density: 1.912 g/cm³
• LogP: 3.98700
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 4.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 365.87141
• Heavy Atom Count: 18
• Complexity: 346

Purity/Quality:

99% ^*data from raw suppliers

2,6-Dibromoanthraquinone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC2=C(C=C1Br)C(=O)C3=C(C2=O)C=C(C=C3)Br

Technology Process of 2,6-Dibromoanthraquinone

There total 11 articles about 2,6-Dibromoanthraquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.4%

2,6-diamino-9,10-anthraquinone (131-14-6,168681-29-6) → 2,6-dibromoanthraquinone (633-70-5)

Guidance literature:

With tert.-butylnitrite; copper(ll) bromide; In acetonitrile; at 65 ℃;

Reference yield: 98.4%

tert.-butylnitrite (540-80-7) + Cu(II)Br + 2,6-diamino-9,10-anthraquinone (131-14-6,168681-29-6) → 2,6-dibromoanthraquinone (633-70-5)

Guidance literature:

With hydrogenchloride;

Reference yield:

2,6-diamino-9,10-anthraquinone (131-14-6,168681-29-6) + copper(II)bromide (7789-45-9) → 2,6-dibromoanthraquinone (633-70-5)

Guidance literature:

In acetonitrile;

upstream raw materials:

ethanol

4-bromo-2-(4-bromo-benzoyl)-benzoic acid

2,6,9,10-tetrabromoanthracene?

2,6-diamino-9,10-anthraquinone

Downstream raw materials:

2,6-bis[2-(4-trifluoromethylphenyl)thiazol-5-yl]anthraquinone

2,6-bis(4-trifluoromethylphenyl)anthraquinone

2,6-bis(diphenylamino)anthraquinone

Refernces

• 1、 De Carvalho, Jo?o Guilherme M.,Fischer, Roland A.,P?thig, Alexander. "Molecular Oxygen Activation by Redox-Switchable Anthraquinone-Based Metal-Organic Frameworks". . p. 4676 - 4682. Retrieved 2021.
• 2、 Moon, Hyunsoo,Jun, Yong Woong,Kim, Dokyoung,Ryu, Hye Gun,Wang, Taejun,Kim, Ki Hean,Huh, Youngbuhm,Jung, Junyang,Ahn, Kyo Han. "A Dipolar Anthracene Dye: Synthesis, Optical Properties and Two-photon Tissue Imaging". . p. 2518 - 2523. Retrieved 2016.
• 3、 Cartwright, Luke,Taylor, Lois. J.,Yi, Hunan,Iraqi, Ahmed,Zhang, Yiwei,Scarratt, Nicholas. W.,Wang, Tao,Lidzey, David. G.. "Triisopropylsilylacetylene-functionalised anthracene-alt-benzothiadiazole copolymers for application in bulk heterojunction solar cells". . p. 101607 - 101615. Retrieved 2015.
• 4、 Santra, Dines Chandra,Bera, Manas Kumar,Sukul, Pradip Kumar,Malik, Sudip. "Charge-Transfer-Induced Fluorescence Quenching of Anthracene Derivatives and Selective Detection of Picric Acid". . p. 2012 - 2019. Retrieved 2016.
• 5、 Power, Gerald,Hodge, Philip,Clarke, Ian D.,Rabjohns, Michael A.,Goodbody, Ian. "Synthesis of poly(anthra-9,10-quinone-2,6-diyl)". . p. 873 - 874. Retrieved 1998.
• 6、 Becuwe, Matthieu,Fédèle, Lionel,Ouari, Olivier,Sauvage, Frédéric,Thiam, Amadou. "Empowering organic-based negative electrode material based on conjugated lithium carboxylate through molecular design". . . Retrieved 2020/04/15.