3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose

Base Information

Chemical Name:3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose
CAS No.:141242-26-4
Molecular Formula:C₃₂H₃₇BrO₆Si
Molecular Weight:625.632
Hs Code.:

Synonyms:3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose

Suppliers and Price of 3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose

There total 6 articles about 3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.1%

: 110920-93-9
3,5-O-benzylidene-6-O-tert-butyldiphenylsilyl-1,2-O-isopropylidene-α-D-glucofuranose

: 141242-26-4
3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose

Guidance literature:: With N-Bromosuccinimide; barium carbonate; In tetrachloromethane; for 4h; Heating;
DOI:10.1016/0008-6215(92)80042-Y

Reference yield:

: 110920-92-8
(3aR,5R,6S,6aR)-5-((R)-2-(tert-butyldiphenylsilyloxy)-1-hydroxyethyl)-2,2-dimethyltetrahydrofuro(3,2-d)(1,3)dioxol-6-ol

: 141242-26-4
3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: ZnCl₂ / 6 h / 20 °C

2: N-bromosuccinimide; BaCO₃ / CCl₄ / 2.5 h / Heating

With N-Bromosuccinimide; barium carbonate; zinc(II) chloride; In tetrachloromethane; 1: acetalation / 2: Bromination;
DOI:10.1080/07328309708006509

Reference yield:

: 100-52-7
benzaldehyde

: 141242-26-4
3-O-benzoyl-5-bromo-6-O-tert-butyldiphenylsilyl-5-deoxy-1,2-O-isopropylidene-β-L-idofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 94.4 percent / fused zinc chloride / 22 h / Ambient temperature

2: 74.1 percent / N-bromosuccinimide, barium carbonate / CCl₄ / 4 h / Heating

With N-Bromosuccinimide; barium carbonate; zinc(II) chloride; In tetrachloromethane;
DOI:10.1016/0008-6215(92)80042-Y