(((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane)

Base Information

Chemical Name:(((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane)
CAS No.:1290537-62-0
Molecular Formula:C₄₈H₆₄O₄Si₂
Molecular Weight:761.205
Hs Code.:

Synonyms:(((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane)

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Chemical Property of (((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane)

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Technology Process of (((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane)

There total 1 articles about (((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1182723-08-5
(2R,2'R)-1,1'-((4S,6S)-dimethyl-1,3-dioxane-4,6-diyl)dipent-4-en-2-ol

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1290537-62-0
(((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane)

Guidance literature:: With 1H-imidazole; In dichloromethane; at 25 ℃; for 18h; Inert atmosphere;
DOI:10.1021/ol200735r

Reference yield:

: 1290537-62-0
(((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane)

: C₄₆H₆₀O₆Si₂

Guidance literature:: With ozone; In methanol; dichloromethane; at -78 ℃; Inert atmosphere;
DOI:10.1021/ol200735r

Reference yield:

: 1290537-62-0
(((2R,2'R)-((4R,6R)-2,2-dimethyl-1,3-dioxane-4,6-diyl)bis(pent-4-ene-2,1-diyl))bis(oxy))bis(tertbutyldiphenylsilane)

: 1290537-67-5
(R)-3-((tert-butyldiphenylsilyl)oxy)-4-((4R,6R)-6-((S)-2-((tert-butyldiphenylsilyl)oxy)but-3-en-1-yl)-2,2-dimethyl-1,3-dioxan-4-yl)butyl pivalate

Guidance literature:: Multi-step reaction with 5 steps

1: ozone / methanol; dichloromethane / -78 °C / Inert atmosphere

2: sodium tetrahydroborate / methanol; dichloromethane / 14 h / -78 - 25 °C / Inert atmosphere

3: pyridine / dichloromethane / 0 - 25 °C / Inert atmosphere

4: tributylphosphine / tetrahydrofuran / 12 h / 25 °C / Inert atmosphere

5: dihydrogen peroxide; sodium hydrogencarbonate / tetrahydrofuran; water / 12 h / 25 °C / Inert atmosphere

With pyridine; sodium tetrahydroborate; tributylphosphine; dihydrogen peroxide; sodium hydrogencarbonate; ozone; In tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1021/ol200735r