1-(1,2-epoxy-1-triphenylsilylethyl)-1-methylsilacyclobutane

Base Information

• Chemical Name: 1-(1,2-epoxy-1-triphenylsilylethyl)-1-methylsilacyclobutane
• CAS No.: 137472-35-6
• Molecular Formula: C₂₄H₂₆OSi₂
• Molecular Weight: 386.641
• Mol file: 137472-35-6.mol

Synonyms:1-(1,2-epoxy-1-triphenylsilylethyl)-1-methylsilacyclobutane

Chemical Property of 1-(1,2-epoxy-1-triphenylsilylethyl)-1-methylsilacyclobutane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 1-(1,2-epoxy-1-triphenylsilylethyl)-1-methylsilacyclobutane

There total 1 articles about 1-(1,2-epoxy-1-triphenylsilylethyl)-1-methylsilacyclobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1,2-epoxyethyl)triphenylsilane (18666-55-2) + 1-chloro-1-methylsiletane (2351-34-0) → 1-(1,2-epoxy-1-triphenylsilylethyl)-1-methylsilacyclobutane (137472-35-6)

Guidance literature:

With sec.-butyllithium; Yield given. Multistep reaction; 1.) cyclohexane, -78 deg C, 1 h, 2.) THF, cyclohexane, -78 deg C, 30 min;

DOI:10.1246/bcsj.68.250

Reference yield: 84.0%

methyllithium (917-54-4) + 1-(1,2-epoxy-1-triphenylsilylethyl)-1-methylsilacyclobutane (137472-35-6) → dimethyl(4-triphenylsilyl-4-pentenyl)silanol (131472-98-5)

Guidance literature:

In tetrahydrofuran; at -78 ℃; for 0.5h;

DOI:10.1016/0040-4039(91)80035-5

upstream raw materials:

(1,2-epoxyethyl)triphenylsilane

1-chloro-1-methylsiletane

Downstream raw materials:

dimethyl(4-triphenylsilyl-4-pentenyl)silanol