bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane

Base Information

Chemical Name:bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane
CAS No.:1016558-77-2
Molecular Formula:C₂₀H₂₈BFN₂
Molecular Weight:326.265
Hs Code.:

Synonyms:bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane

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Chemical Property of bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane

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Technology Process of bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane

There total 2 articles about bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 14275-09-3
4-bromo-3,5-dimethyl-N,N-dimethylaniline

: 109-63-7
trifluoroborane diethyl ether

: 1016558-77-2
bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane

Guidance literature:: With Mg; In tetrahydrofuran; diethyl ether; (N2); Schlenk technique; soln. of aniline and Mg in THF was refluxed for5 h; cooled to room temp.; filtered; slowly added to soln. of B compd. in Et2O at -78°C; warmed to room temp.; stirred overnight; solvent removed (vac.); extd. (hexane); dried (vac.); washed (hexane);
DOI:10.1021/om701249n

Reference yield:

: 109-63-7
boron trifluoride diethyl etherate

: 14275-09-3
4-bromo-3,5-dimethyl-N,N-dimethylaniline

: 1016558-77-2
bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane

Guidance literature:: 4-bromo-3,5-dimethyl-N,N-dimethylaniline; With iodine; magnesium; In tetrahydrofuran; for 2h; Inert atmosphere; Schlenk technique; Reflux;

boron trifluoride diethyl etherate; In tetrahydrofuran; at -78 - 20 ℃; for 18h; Inert atmosphere; Schlenk technique;
DOI:10.1002/chem.201602410

Reference yield: 69.0%

: 1122-58-3
dmap

: 27607-77-8
trimethylsilyl trifluoromethanesulfonate

: 1016558-77-2
bis[4-(N,N-dimethylamino)-2,6-dimethylphenyl]fluoroborane

: 1016558-76-1
(4-Me₂N-2,6-Me₂-C₆H₂)2B(p-dimethylaminopyridine)(O₃SCF₃)

Guidance literature:: In chlorobenzene; (N2); Schlenk technique; soln. of B compd., Me2NC5H4N and Me3SiOTf in chlorobenzene was refluxed overnight; cooled; Et2O added; filtered; washed (Et2O); dried (vac.); elem. anal.;
DOI:10.1021/om701249n