(E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane

Base Information

Chemical Name:(E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane
CAS No.:80399-17-3
Molecular Formula:C₂₀H₃₀O₃SSi
Molecular Weight:378.608
Hs Code.:

Synonyms:(E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane

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Technology Process of (E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane

There total 5 articles about (E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 29193-71-3
methyl 4-(phenylsulfanyl)butanoate

: 80399-17-3
(E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) NCS, 2.) t-BuOK / 1.) CCl₄, reflux, 2.) THF, from -20 deg C to room temp.

2: 86 percent / LiAlH₄ / diethyl ether / Heating

3: 1.) n-BuLi / 1.) hexane room temp., 2.) THF, -78 deg C

4: 1.) t-BuOK, 2.) C₅H₅N / 1.) THF, -20 deg C, 2.) ether

With pyridine; N-chloro-succinimide; lithium aluminium tetrahydride; n-butyllithium; potassium tert-butylate; In diethyl ether;
DOI:10.1021/jo00343a034

Reference yield:

: 63196-76-9,116500-60-8,116500-62-0,144407-72-7
Methyl trans-2-phenylthiocyclopropanecarboxylate

: 80399-17-3
(E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 3 steps

1: 86 percent / LiAlH₄ / diethyl ether / Heating

2: 1.) n-BuLi / 1.) hexane room temp., 2.) THF, -78 deg C

3: 1.) t-BuOK, 2.) C₅H₅N / 1.) THF, -20 deg C, 2.) ether

With pyridine; lithium aluminium tetrahydride; n-butyllithium; potassium tert-butylate; In diethyl ether;
DOI:10.1021/jo00343a034

Reference yield:

: 108-98-5
thiophenol

: 80399-17-3
(E)-2-<3-<2-(trimethylsilyl)oxymethyl-1-thiophenylcyclopropyl>-2-propenyl>-2-methyl-1,3-dioxolane

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) LiH, 2.) H₂SO₄ / 1.) THF, HMPA, room temp.

2: 1.) NCS, 2.) t-BuOK / 1.) CCl₄, reflux, 2.) THF, from -20 deg C to room temp.

3: 86 percent / LiAlH₄ / diethyl ether / Heating

4: 1.) n-BuLi / 1.) hexane room temp., 2.) THF, -78 deg C

5: 1.) t-BuOK, 2.) C₅H₅N / 1.) THF, -20 deg C, 2.) ether

With pyridine; N-chloro-succinimide; lithium aluminium tetrahydride; n-butyllithium; sulfuric acid; potassium tert-butylate; lithium hydride; In diethyl ether;
DOI:10.1021/jo00343a034