1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE

Base Information

• Chemical Name: 1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE
• CAS No.: 21969-12-0
• Molecular Formula: C12H8 Br N O2 S
• Molecular Weight: 310.171
• Hs Code.: 2930909090
• Mol file: 21969-12-0.mol

Synonyms:Sulfide,p-bromophenyl p-nitrophenyl (6CI,7CI,8CI);4-(4-Bromophenylsulfanyl)nitrobenzene; 4-Bromophenyl 4-nitrophenyl sulfide; NSC149667; p-Bromophenyl p-nitrophenyl sulfide

Chemical Property of 1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE

Chemical Property:

• Vapor Pressure: 6.14E-08mmHg at 25°C
• Boiling Point: 452.2°Cat760mmHg
• Flash Point: 227.3°C
• PSA: 71.12000
• Density: 1.63g/cm³
• LogP: 5.03170
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature

Purity/Quality:

97% ^*data from raw suppliers

1-[(4-Bromophenyl)sulfanyl]-4-nitrobenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE

There total 15 articles about 1-[(4-BROMOPHENYL)SULFANYL]-4-NITROBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

p-nitrobenzene iodide (636-98-6) + para-bromobenzenethiol (106-53-6) → 4-bromophenyl 4′-nitrophenyl sulfide (21969-12-0)

Guidance literature:

With potassium hydroxide; tetrabutylammomium bromide; nickel dichloride; at 110 ℃; for 4.5h;

DOI:10.1016/j.tetlet.2007.12.118

Reference yield: 90.0%

para-dinitrobenzene (100-25-4) + para-bromobenzenethiol (106-53-6) → 4-bromophenyl 4′-nitrophenyl sulfide (21969-12-0)

Guidance literature:

With potassium phosphate; 18-crown-6 ether; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1016/j.cclet.2019.07.012

Reference yield: 87.0%

para-bromobenzenethiol (106-53-6) + 4-Fluoronitrobenzene (350-46-9,178603-76-4) → 4-bromophenyl 4′-nitrophenyl sulfide (21969-12-0)

Guidance literature:

With potassium phosphate; at 80 ℃; for 12h; Ionic liquid;

DOI:10.1039/c6gc01742h

upstream raw materials:

4-amino-4'-nitrodiphenyl sulfide

para-bromobenzenethiol

4-chlorobenzonitrile

4-bromo-benzenethiol; potassium salt

Downstream raw materials:

(4-bromophenyl)(4-aminophenyl)thioether

1-bromo-4-((4-nitrophenyl)sulfonyl)benzene

4-bromo-4'-nitro-diphenyl sulphoxide

(4-iodophenyl)(4-nitrophenyl)thioether