carbonyldihydridotris(triphenylarsine)ruthenium

Base Information

Chemical Name:carbonyldihydridotris(triphenylarsine)ruthenium
CAS No.:77170-95-7
Molecular Formula:C₅₅H₄₇As₃ORu
Molecular Weight:1049.81
Hs Code.:

Synonyms:carbonyldihydridotris(triphenylarsine)ruthenium

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Chemical Property of carbonyldihydridotris(triphenylarsine)ruthenium

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Technology Process of carbonyldihydridotris(triphenylarsine)ruthenium

There total 2 articles about carbonyldihydridotris(triphenylarsine)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 16940-66-2
sodium tetrahydroborate

: 15747-11-2,75494-78-9
dichlorocarbonyltris(triphenylarsine)ruthenium(II)

: 75455-75-3,77170-95-7
dihydridocarbonyltris(triphenylarsine)ruthenium(II)

Guidance literature:: In ethanol; refluxing with stirring (1.5 h); cooling, filtration, washing (MeOH, H2O, MeOH, hexane), drying (vac.); elem. anal.;
DOI:10.1016/S0020-1693(00)88880-5

Reference yield: 51.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 14898-67-0
ruthenium(III) chloride trihydrate

: 603-32-7
triphenyl-arsane

: 77170-95-7
carbonyldihydridotris(triphenylarsine)ruthenium

Guidance literature:: With potassium hydroxide; In ethanol; water; (inert atm.); refluxing 20 min; ppt. washing (EtOH, H2O, EtOH, hexane), dissolving (hot C6H6), filtn., solvent removal (vac.), dissolving (cold C6H6), filtn., washing (cold C6H6, hexane), drying (vac.); elem. anal.;
DOI:10.1016/0277-5387(96)00108-8

Reference yield: 80.0%

: 77170-95-7
carbonyldihydridotris(triphenylarsine)ruthenium

: 7732-18-5
water

: 141556-42-5
[1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene

: [Ru(H)2(CO)(H₂O)(bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene))2]

Guidance literature:: In hexane; water; toluene; using Schlenk techniques; heating of soln. of Ru(AsPh3)3(CO)H2 in toluene and 3 equiv. of C3H2N2(C6H2Me3)2 at 75°C for 4 days, cooling toroom temp., evapn. to dryness, addn. of degassed hexane and water, stir ring for 2 h; pptn., filtration, washing with cold hexane, pumping to dryness, isolation of further batch from mother liquor, elem. anal.;
DOI:10.1021/om020684e