carbonyldihydridotris(triphenylarsine)ruthenium

Base Information

• Chemical Name: carbonyldihydridotris(triphenylarsine)ruthenium
• CAS No.: 77170-95-7
• Molecular Formula: C₅₅H₄₇As₃ORu
• Molecular Weight: 1049.81
• Mol file: 77170-95-7.mol

Synonyms:carbonyldihydridotris(triphenylarsine)ruthenium

Chemical Property of carbonyldihydridotris(triphenylarsine)ruthenium

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of carbonyldihydridotris(triphenylarsine)ruthenium

There total 2 articles about carbonyldihydridotris(triphenylarsine)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

sodium tetrahydroborate (16940-66-2) + dichlorocarbonyltris(triphenylarsine)ruthenium(II) (15747-11-2,75494-78-9) → dihydridocarbonyltris(triphenylarsine)ruthenium(II) (75455-75-3,77170-95-7)

Guidance literature:

In ethanol; refluxing with stirring (1.5 h); cooling, filtration, washing (MeOH, H2O, MeOH, hexane), drying (vac.); elem. anal.;

DOI:10.1016/S0020-1693(00)88880-5

Reference yield: 51.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + ruthenium(III) chloride trihydrate (14898-67-0) + triphenyl-arsane (603-32-7) → carbonyldihydridotris(triphenylarsine)ruthenium (77170-95-7)

Guidance literature:

With potassium hydroxide; In ethanol; water; (inert atm.); refluxing 20 min; ppt. washing (EtOH, H2O, EtOH, hexane), dissolving (hot C6H6), filtn., solvent removal (vac.), dissolving (cold C6H6), filtn., washing (cold C6H6, hexane), drying (vac.); elem. anal.;

DOI:10.1016/0277-5387(96)00108-8

Reference yield: 80.0%

carbonyldihydridotris(triphenylarsine)ruthenium (77170-95-7) + water (7732-18-5) + [1,3-bis(2,4,6-trimethylphenyl)imidazol]-2-ylidene (141556-42-5) → [Ru(H)2(CO)(H2O)(bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene))2]

Guidance literature:

In hexane; water; toluene; using Schlenk techniques; heating of soln. of Ru(AsPh3)3(CO)H2 in toluene and 3 equiv. of C3H2N2(C6H2Me3)2 at 75°C for 4 days, cooling toroom temp., evapn. to dryness, addn. of degassed hexane and water, stir ring for 2 h; pptn., filtration, washing with cold hexane, pumping to dryness, isolation of further batch from mother liquor, elem. anal.;

DOI:10.1021/om020684e

upstream raw materials:

sodium tetrahydroborate

dichlorocarbonyltris(triphenylarsine)ruthenium(II)

formaldehyd

ruthenium(III) chloride trihydrate

Downstream raw materials:

Ru(C₆H₄)N₂C(C₆H₅)N₂C₆H₅(CO)(As(C₆H₅)3)2

RuH₂CO(As(C₆H₅)2CH₂)2(As(C₆H₅)3)

RuH₂CO(As(C₆H₅)2CH₂CH₂P(C₆H₅)2)(As(C₆H₅)3)