(Z)-1,2-diphenylvinyl dimethylcarbamate

Base Information

• Chemical Name: (Z)-1,2-diphenylvinyl dimethylcarbamate
• CAS No.: 1208405-05-3
• Molecular Formula: C₁₇H₁₇NO₂
• Molecular Weight: 267.327
• Mol file: 1208405-05-3.mol

Synonyms:(Z)-1,2-diphenylvinyl dimethylcarbamate

Chemical Property of (Z)-1,2-diphenylvinyl dimethylcarbamate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-1,2-diphenylvinyl dimethylcarbamate

There total 1 articles about (Z)-1,2-diphenylvinyl dimethylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

phenyl benzyl ketone (451-40-1) + N,N-Dimethylcarbamoyl chloride (79-44-7) → (Z)-1,2-diphenylvinyl dimethylcarbamate (1208405-05-3)

Guidance literature:

phenyl benzyl ketone; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 - 5 ℃; Inert atmosphere;

N,N-Dimethylcarbamoyl chloride; In N,N-dimethyl-formamide; mineral oil; at 75 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ol9029534

Reference yield: 96.0%

(Z)-1,2-diphenylvinyl dimethylcarbamate (1208405-05-3) + 2-methoxyphenylmagnesium bromide (16750-63-3) → (Z)-(1-(2-methoxyphenyl)ethene-1,2-diyl)dibenzene (1448251-66-8)

Guidance literature:

With N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride; palladium diacetate; In tetrahydrofuran; at 50 ℃; for 3h; stereoselective reaction; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.0c01127

Reference yield: 95.0%

(Z)-1,2-diphenylvinyl dimethylcarbamate (1208405-05-3) + 2-mesitylmagnesium bromide (2633-66-1) → (Z)-1,2-diphenyl-1-(2,4,6-trimethylphenyl)ethene

Guidance literature:

With N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride; palladium diacetate; In tetrahydrofuran; at 50 ℃; for 1h; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.orglett.0c01127

upstream raw materials:

phenyl benzyl ketone

N,N-Dimethylcarbamoyl chloride

Downstream raw materials:

Triphenylethylene

(Z)-(1-(2-methoxyphenyl)ethene-1,2-diyl)dibenzene

(Z)-(1-(o-tolyl)ethene-1,2-diyl)dibenzene