2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene

Base Information

Chemical Name:2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene
CAS No.:351536-23-7
Molecular Formula:C₁₇H₂₂Cl₃F₃OSi
Molecular Weight:433.801
Hs Code.:

Synonyms:2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene

Suppliers and Price of 2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of 2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene

There total 4 articles about 2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2062-26-2,87212-84-8,16642-92-5
3-<4'-(trifluoromethyl)phenyl>-2-propenoic acid

: 351536-23-7
2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene

Guidance literature:: Multi-step reaction with 5 steps

1: K₂CO₃ / acetone / Heating

2: DIBAL / 1 h / 0 °C

3: PDC / dimethylformamide / 1.5 h / 20 °C

4: CCl₃CO₂H / dimethylformamide / 20 °C

5: imidazole / dimethylformamide / 20 °C

With 1H-imidazole; dipyridinium dichromate; diisobutylaluminium hydride; potassium carbonate; trichloroacetic acid; In N,N-dimethyl-formamide; acetone;
DOI:10.1021/jo010068c

Reference yield:

: 20754-22-7
methyl (2E)-3-(4-(trifluoromethyl)phenyl)prop-2-enoate

: 351536-23-7
2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene

Guidance literature:: Multi-step reaction with 4 steps

1: DIBAL / 1 h / 0 °C

2: PDC / dimethylformamide / 1.5 h / 20 °C

3: CCl₃CO₂H / dimethylformamide / 20 °C

4: imidazole / dimethylformamide / 20 °C

With 1H-imidazole; dipyridinium dichromate; diisobutylaluminium hydride; trichloroacetic acid; In N,N-dimethyl-formamide;
DOI:10.1021/jo010068c

Reference yield:

: 95123-61-8
(2E)-3-(4-trifluoromethylphenyl)prop-2-enal

: 351536-23-7
2-tert-butyldimethylsilyloxy-1,1,1-trichloro-4-(4-trifluoromethylphenyl)-3-butene

Guidance literature:: Multi-step reaction with 2 steps

1: CCl₃CO₂H / dimethylformamide / 20 °C

2: imidazole / dimethylformamide / 20 °C

With 1H-imidazole; trichloroacetic acid; In N,N-dimethyl-formamide;
DOI:10.1021/jo010068c