[phenyltris((tert-butylthio)methyl)borate]NiCl

Base Information

Chemical Name:[phenyltris((tert-butylthio)methyl)borate]NiCl
CAS No.:213008-73-2
Molecular Formula:C₂₁H₃₈BClNiS₃
Molecular Weight:491.685
Hs Code.:

Synonyms:[phenyltris((tert-butylthio)methyl)borate]NiCl

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Chemical Property of [phenyltris((tert-butylthio)methyl)borate]NiCl

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Technology Process of [phenyltris((tert-butylthio)methyl)borate]NiCl

There total 1 articles about [phenyltris((tert-butylthio)methyl)borate]NiCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 213008-71-0,301663-26-3
thallium phenyltris((tert-butylthio)methyl)borate

: 83864-14-6
nickel dichloride

: 213008-73-2
[phenyltris((tert-butylthio)methyl)borate]NiCl

Guidance literature:: In dichloromethane; acetone; byproducts: TlCl; addn. of 1 equiv. Tl-complex (in CH2Cl2) to NiCl2 (in Me2CO); elem. anal.;

Reference yield: 61.0%

: 213008-73-2
[phenyltris((tert-butylthio)methyl)borate]NiCl

: 594-09-2
trimethylphosphane

: 326868-96-6
[phenyltris((tert-butylthio)methyl)borate]Ni(I)P(CH₃)3

Guidance literature:: With CH₃Li; In tetrahydrofuran; diethyl ether; (PhTt(tBu))Ni(II)Cl was dissolved in Et2O, cooled to -78°C, soln.PMe3 in THF was added followed by soln. MeLi in Et2O, react. mixt. was stirred for 6 h as soln. warmed to 25°C; solvent was removed under reduced pressure, residue was extd. with pentane and passed trough silica plug; elem. anal.;
DOI:10.1021/ic020441e

Reference yield: 51.0%

: 213008-73-2
[phenyltris((tert-butylthio)methyl)borate]NiCl

: 201230-82-2
carbon monoxide

: 326868-98-8
(phenyltris((tert-butylthio)methyl)borate)carbonylnickel

Guidance literature:: With CH₃Li; In diethyl ether; CO was bubbled through soln. (PhTt(tBu))Ni(II)Cl in Et2O at -78°Cfor 3 min followed by addn. MeLi in Et2O, react. mixt. was stirred for 6 h at 25°C under CO atm; elem. anal.;
DOI:10.1021/ic020441e