Carbazole Violet

Base Information

• Chemical Name: Carbazole Violet
• CAS No.: 6358-30-1
• Molecular Formula: C34H22Cl2N4O2
• Molecular Weight: 589.48
• Hs Code.: 3204.17
• European Community (EC) Number: 228-767-9,613-252-7,640-986-5
• UNII: 8U8Z6628KF
• DSSTox Substance ID: DTXSID2036293
• Nikkaji Number: J1.274B
• Wikipedia: Pigment_violet_23
• Wikidata: Q26706218
• Mol file: 6358-30-1.mol

Synonyms:6358-30-1;Carbazole Violet;Dioxazine Violet;8U8Z6628KF;CI 51319;2,20-dichloro-14,32-diethyl-18,36-dioxa-4,14,22,32-tetrazanonacyclo[19.15.0.03,19.05,17.07,15.08,13.023,35.025,33.026,31]hexatriaconta-1,3,5(17),6,8,10,12,15,19,21,23(35),24,26,28,30,33-hexadecaene;8,18-Dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine;Diindolo(3,2-b:3',2'-m)triphenodioxazine, 8,18-dichloro-5,15-diethyl-5,15-dihydro-;Permanent Violet R;Cyanadur Violet;Heliogen Violet;Dioxazine purple;Permanent Violet;8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo[3,2-b:3',2'-m]triphenodioxazine;Lionol Violet HR;Lionogen Violet RL;Sandorin Violet BL;Vynamon Violet 2B;Hostaperm Violet RL;PV Fast Violet BL;Chromofine Violet RE;Lake Fast Violet RL;Unisperse Violet B-E;Carbazole Violet Crude;Helio Fast Violet BN;FAST VIOLET RL;Lake Fast Violet RLB;EMC Violet RL 10;Monolite Fast Violet R;Heliogen Violet R Toner;Paliogen Violet 5890;Heliofast Red Violet EE;Sumitone Fast Violet RL;Symuler Fast Violet BBL;EB Violet 4B7906;Fastogen Super Violet RN;PV Fast Violet RL-SPE;Sumitone Fast Violet RLS;Carbazole Dioxazine Violet;Symuler Fast Violet BBLN;Fastogen Super Violet RTS;Fastogen Super Violet RVS;Lionogen Violet R 6100;Paliogen Violet L 5890;Sumikacoat Fast Violet RSB;Hostaperm Violet RL Special;Fastogen Super Violet RN-S;Sumitone Fast Violet RL 4R;SCHEMBL342958;UNII-8U8Z6628KF;DTXSID2036293;CARBAZOLE VIOLET [MART.];CI 51319 [INCI];Sanyo Permanent Violet BL-D 422;EINECS 228-767-9;9,19-Dichloro-5,15-diethyl-5,15-dihydro-diindolo[2,3-c:2',3'-n]triphenodioxazine;Hostaperm Violet RL Special 14-4007;FT-0623456;D94662;EC 228-767-9;Q27271021;8,18-Dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)tri- phenodioxazine;Diindolo(3,2-b:3',2'-m-)triphenodioxazine, 8,18-dichloro-5,15-diethyl-5,15-dihydro-

Chemical Property of Carbazole Violet

Chemical Property:

• Melting Point: 385°C (dec.)
• Refractive Index: 1.787
• PSA: 52.55000
• Density: 1.53 g/cm³
• LogP: 9.71160
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 8.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 588.1119813
• Heavy Atom Count: 42
• Complexity: 1180

Purity/Quality:

99.9% ^*data from raw suppliers

PigmentViolet23,Technicalgrade ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN1C2=CC=CC=C2C3=CC4=C(C=C31)OC5=C(C6=NC7=C(C=C8C(=C7)C9=CC=CC=C9N8CC)OC6=C(C5=N4)Cl)Cl
• Uses: Carbazole Violet is used primarily as a shading pigment with copper phthalocyanines and for toning whites in a variety of systems.

Technology Process of Carbazole Violet

There total 2 articles about Carbazole Violet which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,5-bis(9-ethyl-9H-carbazol-3-ylamino)-3,6-dichlorocyclohexa-2,5-diene-1,4-dione (80546-37-8) → 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo (3,2-b: 3',2'-m)triphenodioxazine (215247-95-3) + 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo<3,2-b:3',2'-m>triphenodioxazine (6358-30-1)

Guidance literature:

With sulfuric acid; chloranil; at 120 ℃; Overall yield = 84.8 %; Overall yield = 150 mg; Microwave irradiation;

Reference yield:

9-ethyl-9H-carbazol-3-ylamine (132-32-1) + chloranil (118-75-2) → 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo (3,2-b: 3',2'-m)triphenodioxazine (215247-95-3) + 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo<3,2-b:3',2'-m>triphenodioxazine (6358-30-1)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium acetate / ethanol / 3 h / 45 - 60 °C

2: chloranil; sulfuric acid / 120 °C / Microwave irradiation

With sulfuric acid; sodium acetate; chloranil; In ethanol;

upstream raw materials:

2,5-bis(9-ethyl-9H-carbazol-3-ylamino)-3,6-dichlorocyclohexa-2,5-diene-1,4-dione

9-ethyl-9H-carbazol-3-ylamine

chloranil

Refernces