TRIS(4-METHYL-8-HYDROXYQUINOLINE)ALUMINUM

Base Information

• Chemical Name: TRIS(4-METHYL-8-HYDROXYQUINOLINE)ALUMINUM
• CAS No.: 14752-00-2
• Molecular Formula: C₃₀H₂₄AlN₃O₃
• Molecular Weight: 501.52
• Mol file: 14752-00-2.mol

Synonyms:Aluminum,tris(4-methyl-8-quinolinolato)- (7CI); Aluminum,tris(4-methyl-8-quinolinolato-N1,O8)-; 8-Quinolinol, 4-methyl-, aluminumcomplex; Aluminum Tris(4-methyl-8-quinolinolate);Tris(4-methyl-8-hydroxyquinolato)aluminum;Tris(4-methyl-8-hydroxyquinolinato)aluminum;Tris(4-methyl-8-hydroxyquinolinol)aluminum;Tris(4-methyl-8-quinolinolato)aluminum(III)

Chemical Property of TRIS(4-METHYL-8-HYDROXYQUINOLINE)ALUMINUM

Chemical Property:

• Melting Point: 356°C
• PSA: 66.36000
• LogP: 7.15890

Purity/Quality:

99% ^*data from raw suppliers

TRIS(4-METHYL-8-HYDROXYQUINOLINE)ALUMINUM 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(4-METHYL-8-HYDROXYQUINOLINE)ALUMINUM

There total 2 articles about TRIS(4-METHYL-8-HYDROXYQUINOLINE)ALUMINUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aluminum(III) sulfate + 4-methylquinolin-8-ol (3846-73-9) → aluminum(III) tris(4-methyl-8-quinolinolato) (136779-65-2,14752-00-2)

Guidance literature:

In methanol; water; at 70 ℃; for 20h;

DOI:10.1177/1747519820973601

Reference yield:

aluminium trichloride (7446-70-0) + 4-methylquinolin-8-ol (3846-73-9) → aluminum(III) tris(4-methyl-8-quinolinolato) (136779-65-2,14752-00-2)

Guidance literature:

With ammonium acetate; In water; AlCl3 was mixed with the aq. solution of the ligand buffered with ammonium acetate in a 1:3 molar ratio; recrystn. from MeOH; differential scanning calorimetry, thermal gravimetric anal.;

DOI:10.1021/ja010120m

upstream raw materials:

aluminium trichloride

4-methylquinolin-8-ol

Refernces

• 1、 Sapochak,Padmaperuma,Washton,Endrino,Schmett,Marshall,Fogarty,Burrows,Forrest. "Effects of systematic methyl substitution of metal (III) tris(n-methyl-8-quinolinolato) chelates on material properties for optimum electroluminescence device performance". . p. 6300 - 6307. Retrieved 2007/10/03.