Ethyl 4-bromoacetoacetate

Base Information

Chemical Name:Ethyl 4-bromoacetoacetate
CAS No.:13176-46-0
Molecular Formula:C6H9BrO3
Molecular Weight:209.04
Hs Code.:2918300090
Mol file:13176-46-0.mol

Synonyms:Acetoaceticacid, 4-bromo-, ethyl ester (6CI,7CI,8CI);4-Bromo-3-oxobutanoic acid ethylester;Ethyl (bromoacetyl)acetate;Ethyl 4-bromo-3-oxobutanoate;Ethyl4-bromo-3-oxobutyrate;

Suppliers and Price of Ethyl 4-bromoacetoacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
Ethyl 4-Bromoacetoacetate
250mg
$ 319.00

TRC
Ethyl4-Bromoacetoacetate
250mg
$ 55.00

TRC
Ethyl4-Bromoacetoacetate
1g
$ 70.00

SynQuest Laboratories
Ethyl 4-bromo-3-oxobutanoate 90%
5 g
$ 128.00

SynQuest Laboratories
Ethyl 4-bromo-3-oxobutanoate 90%
1 g
$ 48.00

Oakwood
4-Bromo-3-oxo-butyric acid ethyl ester
10g
$ 400.00

Oakwood
4-Bromo-3-oxo-butyric acid ethyl ester
250mg
$ 30.00

Oakwood
4-Bromo-3-oxo-butyric acid ethyl ester
1g
$ 60.00

Matrix Scientific
Ethyl 4-bromo-3-oxobutanoate 90%
5g
$ 260.00

Matrix Scientific
Ethyl 4-bromo-3-oxobutanoate 90%
1g
$ 85.00

Total 91 raw suppliers

Chemical Property of Ethyl 4-bromoacetoacetate

Chemical Property:

Appearance/Colour:white crystalline power
Vapor Pressure:0.0616mmHg at 25°C
Refractive Index:1.469
Boiling Point:231.6 °C at 760 mmHg
PKA:9.56±0.46(Predicted)
Flash Point:93.9 °C
PSA：43.37000
Density:1.478 g/cm³
LogP:0.90360
Storage Temp.:2-8°C(protect from light)

Purity/Quality:

99% ^*data from raw suppliers

Ethyl 4-Bromoacetoacetate ^*data from reagent suppliers

Safty Information:

Pictogram(s): F
Hazard Codes:F

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Ethyl 4-bromoacetoacetate

There total 14 articles about Ethyl 4-bromoacetoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.54%

: 141-97-9
ethyl acetoacetate

: 13176-46-0
4-bromoethyl acetoacetate

Guidance literature:: With bromine; In dichloromethane; at -5 - 5 ℃; for 2h;

Reference yield: 90.0%

: 141-97-9
ethyl acetoacetate

: 13176-46-0
4-bromoethyl acetoacetate

: ethyl 4-bromoacetoacetate

Guidance literature:: ethyl acetoacetate; With bromine; In acetic acid; at 20 ℃; for 0.5h;

With hydroquinone; In acetic acid; at 20 ℃; for 1h; Further stages.;
DOI:10.1021/ol0271638

Reference yield: 84.0%

: 674-82-8,2130-41-8
4-methyleneoxetan-2-one

: 64-17-5
ethanol

: 13176-46-0
4-bromoethyl acetoacetate

Guidance literature:: 4-methyleneoxetan-2-one; With bromine; In dichloromethane; at -20 - -10 ℃; Inert atmosphere;

ethanol; With pyridine; In dichloromethane; at -10 - 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/acs.joc.6b01528