1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene

Base Information

Chemical Name:1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene
CAS No.:374934-77-7
Molecular Formula:C₃₀H₅₂B₂O₄
Molecular Weight:498.362
Hs Code.:

Synonyms:1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene

Suppliers and Price of 1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Chem-Impex
1,4-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,5-dihexylbenzene,≥98%(GC) ≥98%(GC)
1G
$ 157.25

Total 12 raw suppliers

Chemical Property of 1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

1,4-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,5-dihexylbenzene,≥98%(GC) ≥98%(GC) ^*data from reagent suppliers

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Hazard Codes:

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Technology Process of 1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene

There total 4 articles about 1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 162715-91-5
1,4-dihexyl-2,5-diiodobenzene

: 73183-34-3
bis(pinacol)diborane

: 374934-77-7
1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; potassium acetate; In N,N-dimethyl-formamide; at 90 ℃; for 48h;
DOI:10.1021/acs.inorgchem.5b02757

Reference yield: 67.0%

: 117635-21-9
1,4-dibromo-2,5-di-n-hexylbenzene

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 374934-77-7
1,4-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-2,5-di-n-hexylbenzene

Guidance literature:: With Pd₂(C₆H₅CHCHCOCHCHC₆H₅)3*CHCl₃; CH₃P(C(CH₃)3)2; N(CH₂CH₃)3; In toluene; N2, Schlenk tecgnique; PMe(tBu)2 in toluene added to Pd compd. in toluene at 0°C, stirring at room temp. for 2 h, Et3N added at -196°C, successive addn. of bromo compd., toluene, and B compd. at room temp., heating at 90°C for 4 d; cooling to room temp., addn. of satd. aq. NH4Cl, org. layer sepd., aq. phase extd. with ether, combined org. phases dried over Na2SO4, filtration, filtrate evapd., recrystn. from hot MeOH, dissolved in hexane. filtration, evapn.; elem. anal.;
DOI:10.1039/c0dt01271h