Cyclohexylazanium;bromide

Base Information

• Chemical Name: Cyclohexylazanium;bromide
• CAS No.: 26227-54-3
• Molecular Formula: C6H14BrN
• Molecular Weight: 180.088
• Hs Code.: 2921300090
• Mol file: 26227-54-3.mol

Synonyms:

Chemical Property of Cyclohexylazanium;bromide

Chemical Property:

• Vapor Pressure: 8.07mmHg at 25°C
• Melting Point: 196-199 °C
• Refractive Index: nD20 1.4585
• Boiling Point: 134.5 °C at 760 mmHg
• Flash Point: 32.2 °C
• PSA: 26.02000
• Density: 0.868 g/ml
• LogP: 2.93620
• Storage Temp.: 2-8°C
• Sensitive.: Hygroscopic
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 179.03096
• Heavy Atom Count: 8
• Complexity: 46.1

Purity/Quality:

99% ^*data from raw suppliers

CYCLOHEXYLAMINE HYDROBROMIDE ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(CC1)[NH3+].[Br-]

Technology Process of Cyclohexylazanium;bromide

There total 6 articles about Cyclohexylazanium;bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

trimethylsilyl bromide (2857-97-8) + t-BuPhP(S)S(1-)*(1+)NH3C6H11 (107487-34-3) → cyclohexylammonium bromide (26227-54-3) + trimethylsilyl t-butylphenyldithiophosphinate (107487-35-4)

Guidance literature:

In tetrachloromethane;

DOI:10.1016/S0040-4020(01)87438-X

Reference yield: 59.0%

[NiBr2(cyclohexylamine)4] + cyclohexylamine (108-91-8,157973-60-9) → N,N'-dicyclohexyloxamide (3299-64-7) + cyclohexylammonium bromide (26227-54-3) + 1,3-Dicyclohexylurea (2387-23-7) + tetracarbonyl nickel (13463-39-3,71564-36-8)

Guidance literature:

With carbon monoxide; In tetrahydrofuran; diethyl ether; addn. of RNH2 to suspn. of complex, CO (40 bar), warmed up to 45°C, 20h, hydrolysis with H2SO4, sepn. of organic phase, dried, crystn. of organic products from hexane/CHCl3 = 20/1;

DOI:10.1016/S0022-328X(00)99113-7

Reference yield:

cyclohexylamine (108-91-8,157973-60-9) → cyclohexylammonium bromide (26227-54-3)

Guidance literature:

With hydrogen bromide; In water; for 0.333333h;

DOI:10.1016/j.jallcom.2017.01.032

upstream raw materials:

trimethylsilyl bromide

t-BuPhP(S)S^(1-)*⁽¹⁺⁾NH₃C₆H₁₁

1-ethyl-2-bromo-pyridinium; bromide

cyclohexylamine

Downstream raw materials:

N-cyclohexylthiourea

1,3-dicyclohexylthiourea

N-cyclohexyl-N,N,N-trimethylammonium bromide

N-butylcyclohexylamine

Refernces

SYNTHESIS AND CRYSTAL STRUCTURE OF THE FERROMAGNETIC CHAIN SYSTEM (C₆D₁₁ND₃)CuBr₃.

10.1016/0022-3697(87)90030-8

This research presents a comprehensive study on the synthesis and crystal structure of the ferromagnetic chain system (C,D,,ND,)CuBr, also known as perdeutero cyclohexylammonium copper(II) bromide (CHAB-D,,). The purpose of the study was to understand the one-dimensional S = 1/2 Heisenberg ferromagnet properties of this compound and to determine its crystal structure using neutron diffraction. The researchers synthesized single crystals of CHAB-D,, and found that its crystal structure is isomorphic with that of its hydrogenated counterpart, CHAC, with orthorhombic symmetry and space group P2,2,2,. The ferromagnetic Cu-chains run along the c-direction, with two bromine ligands forming symmetrical bridges between copper ions. The study concluded that the deuterated compound offers the possibility to study an almost perfect realization of a ferromagnetic 1D S = 1/2 XXZ system using neutron scattering techniques, and that the magnetic properties of the deuterated and hydrogenated versions of CHAB are identical within experimental accuracy limits. Key chemicals used in the process included cyclohexylammonium bromide, copper(II) bromide, and partially deuterated n-propanol as a solvent.