PhN=P(Ph)2CH(C₆H₄)2

Base Information

• Chemical Name: PhN=P(Ph)2CH(C₆H₄)2
• CAS No.: 912636-33-0
• Molecular Formula: C₃₁H₂₄NP
• Molecular Weight: 441.512
• Mol file: 912636-33-0.mol

Synonyms:PhN=P(Ph)2CH(C₆H₄)2

Chemical Property of PhN=P(Ph)2CH(C₆H₄)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of PhN=P(Ph)2CH(C₆H₄)2

There total 1 articles about PhN=P(Ph)2CH(C₆H₄)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Phenyl azide (622-37-7) + diphenyl(9-fluorenyl)phosphine (54458-23-0) → PhN=P(Ph)2CH(C6H4)2 (912636-33-0)

Guidance literature:

Inert atmosphere;

DOI:10.1021/om300263p

Reference yield: 95.0%

PhN=P(Ph)2CH(C6H4)2 (912636-33-0) + tetrabenzylzirconium(IV) (24356-01-2) → [Zr(benzyl)3(Ph2P(fluorenyl)NPh)] (1003323-51-0)

Guidance literature:

In toluene; byproducts: C6H5CH3; (Ar); using Schlenk techniques; heating of soln. of PhNPPh2(fluorenyl) and ZrBn4 at 90°C in the absence of light for 5 h; evapn. under vac.;

DOI:10.1021/om700974g

Reference yield: 90.0%

di-μ-chlorobis(norbornadiene)dirhodium(I) + PhN=P(Ph)2CH(C6H4)2 (912636-33-0) → [Rh(PhNP(Ph)2C(C6H4)2)(norbornadiene)] (912636-34-1,912636-36-3)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; (Ar); std. Schlenk technique; soln. of n-BuLi in hexanes was added to soln. of ligand in THF at -78°C; stirred at room temp. for 30 min; cooled to 0°C; soln. of Rh complex (0.5 equiv.) in THF was added;warmed (room temp.); stirred for 2 h; solvent removed (vac.); extd. (CH2Cl2); evapd.; elem. anal.;

DOI:10.1021/om0605377

upstream raw materials:

Phenyl azide

diphenyl(9-fluorenyl)phosphine

Downstream raw materials:

[Rh(PhNP(Ph)2C(C₆H₄)2)(norbornadiene)]

[Zr(benzyl)3(Ph₂P(fluorenyl)NPh)]

Sc(C₄H₈O)(CH₂Si(CH₃)3)2C₁₃H₈P(C₆H₅)2NC₆H₅