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(2S)-(+)-Glycidyl tosylate

Base Information Edit
  • Chemical Name:(2S)-(+)-Glycidyl tosylate
  • CAS No.:70987-78-9
  • Molecular Formula:C10H12O4S
  • Molecular Weight:228.269
  • Hs Code.:29109000
  • European Community (EC) Number:417-210-7,627-364-9
  • NSC Number:636971
  • UNII:5R5A4KBQ99
  • DSSTox Substance ID:DTXSID601029330
  • Nikkaji Number:J523.141H
  • ChEMBL ID:CHEMBL1986003
  • Mol file:70987-78-9.mol
(2S)-(+)-Glycidyl tosylate

Synonyms:(2R)-glycidyl tosylate;(2S)-glycidyl tosylate;glycidyl tosylate

Suppliers and Price of (2S)-(+)-Glycidyl tosylate
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • TRC
  • (2S)-(+)-Glycidyl tosylate
  • 25g
  • $ 310.00
  • TCI Chemical
  • (2S)-(+)-Glycidyl p-Toluenesulfonate >98.0%(GC)
  • 5g
  • $ 54.00
  • TCI Chemical
  • (2S)-(+)-Glycidyl p-Toluenesulfonate >98.0%(GC)
  • 25g
  • $ 160.00
  • SynQuest Laboratories
  • (2S)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
  • 100 g
  • $ 568.00
  • SynQuest Laboratories
  • (2S)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
  • 5 g
  • $ 128.00
  • SynQuest Laboratories
  • (2S)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
  • 25 g
  • $ 216.00
  • Sigma-Aldrich
  • (2S)-(+)-Glycidyl tosylate 98%
  • 5g
  • $ 98.00
  • Sigma-Aldrich
  • (2S)-(+)-Glycidyl tosylate 98%
  • 25g
  • $ 277.00
  • Medical Isotopes, Inc.
  • (2S)-(+)-Glycidyl tosylate
  • 50 g
  • $ 1380.00
  • Medical Isotopes, Inc.
  • (2S)-(+)-Glycidyl tosylate
  • 5 g
  • $ 610.00
Total 89 raw suppliers
Chemical Property of (2S)-(+)-Glycidyl tosylate Edit
Chemical Property:
  • Appearance/Colour:white to light yellow crystal powder 
  • Melting Point:45-48 °C 
  • Refractive Index:1.5400 (estimate) 
  • Boiling Point:370.5 °C at 760 mmHg 
  • Flash Point:177.9 °C 
  • PSA:64.28000 
  • Density:1.31 g/cm3 
  • LogP:2.17990 
  • Storage Temp.:2-8°C 
  • Solubility.:Dioxane (Slightly), DMSO (Slightly), Methanol (Slightly) 
  • Water Solubility.:decomposes 
  • XLogP3:1.1
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:4
  • Rotatable Bond Count:4
  • Exact Mass:228.04563003
  • Heavy Atom Count:15
  • Complexity:298
Purity/Quality:

99.9% *data from raw suppliers

(2S)-(+)-Glycidyl tosylate *data from reagent suppliers

Safty Information:
  • Pictogram(s): ToxicT, DangerousN, IrritantXi 
  • Hazard Codes:T,N,Xi 
  • Statements: 45-41-43-51/53-68 
  • Safety Statements: 53-45-61 
MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)OCC2CO2
  • Isomeric SMILES:CC1=CC=C(C=C1)S(=O)(=O)OC[C@@H]2CO2
  • Uses (2S)-(+)-Glycidyl tosylate is protected Glycidol, used as an intermediate in the preparation of neurochemicals. Used in the first enantioselective synthesis of (R)- and (S)-4-acetyl-3-(hydroxymethyl)-3,4-dihydro-2H-pyrido[3,2-b]oxazines.
Technology Process of (2S)-(+)-Glycidyl tosylate

There total 8 articles about (2S)-(+)-Glycidyl tosylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With dmap; triethylamine; In dichloromethane; at 0 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1021/acs.joc.5b01323
Guidance literature:
With hydrogenchloride; N,N-dimethylamino-pyridine; potassium carbonate; triethylamine; In water;
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