tetramethylammonium trichloromercurate

Base Information

• Chemical Name: tetramethylammonium trichloromercurate
• CAS No.: 4473-11-4
• Molecular Formula: C₄H₁₂N*Cl₃Hg
• Molecular Weight: 381.095
• Mol file: 4473-11-4.mol

Synonyms:tetramethylammonium trichloromercurate

Chemical Property of tetramethylammonium trichloromercurate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetramethylammonium trichloromercurate

There total 6 articles about tetramethylammonium trichloromercurate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

tetramethylammonium tetrachloroplatinate(II) + ((CH3O)3(NO2)2C6)2Hg → tetramethylammonium trichloromercurate (4473-11-4) + cis-[Me4N][Pt(C6(NO2)2-2,6-(OMe)3-3,4,5-κ2-C,O)(C6(NO2)2-2,6-(OMe)3-3,4,5-κ1-C)Cl] (727730-58-7)

Guidance literature:

In acetone; Hg compd. (1 equiv.) added to suspn. of Pt complex in acetone; stirred at 150°C for 1 h; concd. to dryness; CH2Cl2 added; filtered; filtrate concd.; Et2O added; filtered; solid air dried; elem. anal.;

DOI:10.1021/om049801r

Reference yield: 81.0%

[2,2]bipyridinyl (366-18-7) + [Me4N]2[PdCl2(μ-Cl)]2 + C6H3(CH(OCH3)2)2HgCl → tetramethylammonium trichloromercurate (4473-11-4) + [Pd(C6H3(CH(OMe)2)2-2,5)Cl(2,2'-bipyridine)] (680580-52-3)

Guidance literature:

With (CH₃)4NCl; In acetone; (N2); stirring a mixt. of mercury compd., palladium complex and ammoniumsalt in acetone for 1 h at room temp., then for 4.5 h at 0°C, fi ltration through Celite into a soln. of bpy in acetone, stirring for 45 min; evapn., addn. of CH2Cl2, filtration through Celite, concn., addn. of Et2O, n-hexane, filtration, washing with n-hexane, air drying; elem. anal.;

DOI:10.1021/om0342964

Reference yield: 64.0%

trans-bis(triphenylphosphine)palladium dichloride (28966-81-6) + C6H3(CHS2CH2CH2)2HgCl → tetramethylammonium trichloromercurate (4473-11-4) + [Pd(κ2-C,S-C6H3((CHSCH2CH2S))2-2,5)Cl(PPh3)] (680580-53-4)

Guidance literature:

With (CH₃)4NCl; In 1,4-dioxane; acetone; byproducts: P(C6H5)3; (N2); heating a mixt. of mercury compd., palladium complex and ammonium salt in acetone and dioxane at 76°C for 7 h, cooling to room temp.; filtration through Celite, evapn., addn. of CH2Cl2, filtration through Celite, concn., filtration, addn. of Et2O, hexane, pentane, concn., filtration, chromy. (Al2O3, acetone/CH2Cl2), not purified; elem. anal.;

DOI:10.1021/om0342964

upstream raw materials:

[HgCl(2,5-diformylphenyl)]

tetramethlyammonium chloride

[2,2]bipyridinyl

trans-bis(triphenylphosphine)palladium dichloride