Mercury, chloro(2,5-diformylphenyl)-

Base Information

• Chemical Name: Mercury, chloro(2,5-diformylphenyl)-
• CAS No.: 198643-97-9
• Molecular Formula: C8H5ClHgO2
• Molecular Weight: 369.17
• Mol file: 198643-97-9.mol

Synonyms:

Chemical Property of Mercury, chloro(2,5-diformylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mercury, chloro(2,5-diformylphenyl)-

There total 1 articles about Mercury, chloro(2,5-diformylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

terephthalaldehyde, (623-27-8) + sodium chloride (7647-14-5) + mercury(II) oxide (12653-71-3) → [HgCl(2,5-diformylphenyl)] (198643-97-9)

Guidance literature:

In perchloric acid; aq. HClO4; i) terephthalaldehyde + HgO, 60% aq. HClO4, 95°C; ii) aq. NaCl;

DOI:10.1021/om970583u

Reference yield: 83.0%

[HgCl(2,5-diformylphenyl)] (198643-97-9) + hydroxylamine hydrochloride (5470-11-1) → [HgCl(C6H3(CH=NOH)2-2,5)] (198644-09-6)

Guidance literature:

With NaOH; In methanol; byproducts: H2O; excess of hydroxylamine, stirring for 15 min at room temp.; evapn., washing (H2O), filtration, drying; elem. anal.;

DOI:10.1021/om970583u

Reference yield: 66.0%

[HgCl(2,5-diformylphenyl)] (198643-97-9) + trimethyl orthoformate (149-73-5) → C6H3(CH(OCH3)2)2HgCl

Guidance literature:

With H₂SO₄; In methanol; (N2); react. mecury compd. with orthoformate and 96% H2SO4 in methanol for 24 h at room temp.; addn. of satd. aq. NaHCO3 and CH2Cl2, sepn., washing org. phase with aq.NaHCO3, drying (MgSO4), filtration, evapn., dissolving in Et2O, addn. o f hexane and pentane, evapn., repeated trituration with n-pentane, decantation, drying in vac.; elem. anal.;

DOI:10.1021/om0342964

upstream raw materials:

terephthalaldehyde,

sodium chloride

mercury(II) oxide

Downstream raw materials:

[HgCl(C₆H₃(CH=NOH)2-2,5)]

tetramethylammonium trichloromercurate

[Hg(2,5-diformylphenyl)2]

trans-PdCl(PPh₃)2(C₆H₃(CO₂H)2-2,5)