2-Butylboronic acid

Base Information

Chemical Name:2-Butylboronic acid
CAS No.:88496-88-2
Molecular Formula:C4H11 B O2
Molecular Weight:101.941
Hs Code.:2931900090
European Community (EC) Number:846-011-1
Mol file:88496-88-2.mol

Synonyms:2-Butylboronic acid;88496-88-2;sec-butylboronic acid;Buntane-2-boronic acid;n-Buntane-2-boronic acid;(BUTAN-2-YL)BORONIC ACID;MFCD06656265;Boronic acid, B-butyl-;butan-2-ylboronic acid;Boronic acid, (1-methylpropyl)-;2-Butylboronicacid;sec-Butylboronicacid;2-BUTANEBORONIC ACID;SCHEMBL1454206;sec-Butylboronic acid, >=95%;AKOS015841873;AB25482;AM85121;CS-W011315;AM808120;AS-11307;SY030879;EN300-1245375;A842629

Suppliers and Price of 2-Butylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-Butylboronicacid
1g
$ 75.00

Sigma-Aldrich
sec-Butylboronic acid ≥95%
1g
$ 57.70

Sigma-Aldrich
sec-Butylboronic acid ≥95%
5g
$ 157.00

Crysdot
sec-Butylboronic acid 97%
5g
$ 76.00

Crysdot
sec-Butylboronic acid 97%
25g
$ 228.00

Crysdot
sec-Butylboronic acid 97%
10g
$ 129.00

Chemenu
sec-Butylboronic acid 96%
25g
$ 118.00

Biosynth Carbosynth
2-Butylboronicacid
1 g
$ 57.00

Biosynth Carbosynth
2-Butylboronicacid
2 g
$ 92.00

Biosynth Carbosynth
2-Butylboronicacid
5 g
$ 160.00

Total 66 raw suppliers

Chemical Property of 2-Butylboronic acid

Chemical Property:

Vapor Pressure:0.27mmHg at 25°C
Melting Point:85-89 °C
Refractive Index:1.398
Boiling Point:180 °C at 760 mmHg
PKA:10.59±0.43(Predicted)
Flash Point:62.7 °C
PSA：40.46000
Density:0.91 g/cm³
LogP:0.25930
Storage Temp.:2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:102.0852098
Heavy Atom Count:7
Complexity:47

Purity/Quality:

98% ^*data from raw suppliers

2-Butylboronicacid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C(C)CC)(O)O
Uses Reactant for:? ;Preparation of alkyl- and aryl quinones via silver nitrate-catalyzed coupling with quinones1? ;Preparation of arenes by coupling reactions with aryl bromides and chlorides in the presence of palladium complexes of a (pentaphenylferrocenyl)di(tert-butyl)phosphine2 suzuki reaction

Technology Process of 2-Butylboronic acid

There total 2 articles about 2-Butylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 2-isobutyl-4,6,6-trimethyl-1,3,2-oxazaborinane

: 75-05-8,26809-02-9
acetonitrile

: 88496-88-2
1-methylpropylboronic acid

: 2,4,6,6-tetramethyl-1,4,5,6-tetrahydropyrimidine

Guidance literature:: In hexane; sulfuric acid; solvents cooling to 0°C, acetonitrile and then B-compd. slow addn., stirring (0°C, 5 h), mixture pouring to crushed ice; resulting soln. extracting with chloroform, B-compd. isolation from chloroform extract by evapn., organic product obtaining from aq. layer;

Reference yield:

: 121-43-7,63156-11-6
Trimethyl borate

: 671795-46-3
sec-butylmagnesium bromide

: 88496-88-2
1-methylpropylboronic acid

Guidance literature:: DOI:10.1021/ja01576a026

Reference yield: 94.0%

: 88496-88-2
1-methylpropylboronic acid

: 95-66-9
2,4-dimethylchlorobenzene

: 1483-60-9
1-(sec-butyl)-2,4-dimethylbenzene

Guidance literature:: With methanesulfonato tri(tert-butyl)phosphine (2'-amino-1,1‘-biphenyl-2-yl) palladium (II); potassium carbonate; In water; toluene; at 100 ℃; for 24h; Sealed tube; Inert atmosphere;
DOI:10.1021/ja508815w