1483-60-9

Basic information

• Product Name: BENZENE,2,4-DIMETHYL-1-(1-METH
• Synonyms: BENZENE,2,4-DIMETHYL-1-(1-METH;2,4-Dimethyl-1-(1-methylpropyl)benzene
• CAS NO: 1483-60-9
• Molecular Formula: C₁₂H₁₈
• Molecular Weight: 0
• Mol File: 1483-60-9.mol
• Article Data: 4

Chemical Properties

• Melting Point: -25.43°C (estimate)
• Boiling Point: 224°C (estimate)
• Flash Point: 81.3°C
• Appearance: /
• Density: 0.8664
• Vapor Pressure: 0.17mmHg at 25°C
• Refractive Index: 1.4939
• CAS DataBase Reference: BENZENE,2,4-DIMETHYL-1-(1-METH(CAS DataBase Reference)
• NIST Chemistry Reference: BENZENE,2,4-DIMETHYL-1-(1-METH(1483-60-9)
• EPA Substance Registry System: BENZENE,2,4-DIMETHYL-1-(1-METH(1483-60-9)

Safety Data

• Hazardous Substances Data: 1483-60-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H18/c1-5-10(3)12-7-6-9(2)8-11(12)4/h6-8,10H,5H2,1-4H3

Upstream product

• 715-11-7 2-tosyloxybutane 
• 108-38-3 m-xylene 
• 583-70-0 1-bromo-2,4-dimethylbenzene 
• 142509-27-1 5-(1-methylpropyl)-1-aza-5-stannabicyclo[3.3.3]undecane 
• 2528-45-2 Tri-sec-butyl phosphate 
• 104-15-4 toluene-4-sulfonic acid 
• 126-73-8 phosphoric acid tributyl ester 
• 598-30-1 sec.-butyllithium 
• 87241-53-0 2,4-dimethylphenyl nonaflate 
• 87241-52-9 2,4-dimethylphenyl trifluoromethanesulfonate 
• 925-90-6 ethylmagnesium bromide 
• 89-74-7 2,4-dimethylacetophenone. 
• 78-92-2 iso-butanol 
• 95-66-9 2,4-dimethylchlorobenzene 

Downstream Products

• 39568-70-2 1,2,3,5-tetrabromo-4,6-dimethyl-benzene 
• 939-37-7 1-(sec-butyl)-3,5-dimethylbenzene 
• 98-19-1 5-tert-Butyl-m-xylene 

Relevant articles and documents

Stereospecific Pd-catalyzed cross-coupling reactions of secondary alkylboron nucleophiles and aryl chlorides

We report the development of a Pd-catalyzed process for the stereospecific cross-coupling of unactivated secondary alkylboron nucleophiles and aryl chlorides. This process tolerates the use of secondary alkylboronic acids and secondary alkyltrifluoroborates and occurs without significant isomerization of the alkyl nucelophile. Optically active secondary alkyltrifluoroborate reagents undergo cross-coupling reactions with stereospecific inversion of configuration using this method.

REACTION OF PHOSPHORUS OXYACID ESTERS WITH p-TOLUENESULFONIC ACID

The reaction of primary alkyl esters of phosphorus oxyacids with p-toluenesulfonic acid (TsOH) in refluxing solvents gave the corresponding p-toluenesulfonates (TsOR).We found that the secondary alkyl esters reacted with TsOH at lower temperature (r.t.-40 deg C) to afford TsORs in good yields.It is suggested that sulfonic acids may be useful for the selective dealkylation of mixed esters.Keywords-p-toluenesulfonic acid; p-toluenesulfonate; trialkyl phosphate; trialkyl phosphite; dialkyl phenylphosphonate; transesterification; dealkylation; solvolysis.