Ir(CO)Cl(P(C₆H₅)3)2(tetrafluorobutatriene)

Base Information

• Chemical Name: Ir(CO)Cl(P(C₆H₅)3)2(tetrafluorobutatriene)
• CAS No.: 946621-57-4
• Molecular Formula: C₄₁H₃₀ClF₄IrOP₂
• Molecular Weight: 904.303
• Mol file: 946621-57-4.mol

Synonyms:Ir(CO)Cl(P(C₆H₅)3)2(tetrafluorobutatriene)

Chemical Property of Ir(CO)Cl(P(C₆H₅)3)2(tetrafluorobutatriene)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ir(CO)Cl(P(C₆H₅)3)2(tetrafluorobutatriene)

There total 1 articles about Ir(CO)Cl(P(C₆H₅)3)2(tetrafluorobutatriene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

bis(triphenylphosphine)iridium(I) carbonyl chloride (15318-31-7,14871-41-1,59246-46-7) + 1,1,4,4-tetrafluorobuta-1,2,3-triene (2252-95-1) + dichloromethane (75-09-2) → Ir(CO)Cl(P(C6H5)3)2(tetrafluorobutatriene) (946621-57-4)

Guidance literature:

In toluene; Schlenk technique; anhydrous toluene and tetrafluorobutatriene condensedinto evacuated flask contg. Vaska-complex cooled with liquid N2, warmed to room temp., stirred for 4 h; evapd. under vac., residue dissolved in CH2Cl2, soln. filtered, hexane added, cooled at -35°C for several d, crystals of CH2Cl2 solvate sepd., dried under vac.; elem. anal.;

DOI:10.1002/anie.200701081

Reference yield:

Ir(CO)Cl(P(C6H5)3)2(tetrafluorobutatriene) (946621-57-4) + dichloromethane (75-09-2) → Ir(CO)Cl(P(C6H5)3)2(tetrafluorobutatriene)*CH2Cl2 (946842-15-5)

Guidance literature:

In dichloromethane; on recrystn. from CH2Cl2;

DOI:10.1002/anie.200701081

upstream raw materials:

bis(triphenylphosphine)iridium(I) carbonyl chloride

1,1,4,4-tetrafluorobuta-1,2,3-triene

dichloromethane

Downstream raw materials:

Ir(CO)Cl(P(C₆H₅)3)2(tetrafluorobutatriene)*CH₂Cl₂

Refernces