Fe(CH₃Si(C₆H₃(Si(CH₃)3)S)3)(C₄H₈O)^(1-)*(C₆H₅)4P⁽¹⁺⁾=[Fe(CH₃Si(C₆H₃(S)(Si(CH₃)3))3)(C₄H₈O)][(C₆H₅)4P]

Base Information

• Chemical Name: Fe(CH₃Si(C₆H₃(Si(CH₃)3)S)3)(C₄H₈O)^(1-)*(C₆H₅)4P⁽¹⁺⁾=[Fe(CH₃Si(C₆H₃(S)(Si(CH₃)3))3)(C₄H₈O)][(C₆H₅)4P]
• CAS No.: 695202-95-0
• Molecular Formula: C₂₄H₂₀P*C₃₂H₄₇FeOS₃Si₄
• Molecular Weight: 1051.51
• Mol file: 695202-95-0.mol

Synonyms:Fe(CH₃Si(C₆H₃(Si(CH₃)3)S)3)(C₄H₈O)^(1-)*(C₆H₅)4P⁽¹⁺⁾=[Fe(CH₃Si(C₆H₃(S)(Si(CH₃)3))3)(C₄H₈O)][(C₆H₅)4P]

Chemical Property of Fe(CH₃Si(C₆H₃(Si(CH₃)3)S)3)(C₄H₈O)^(1-)*(C₆H₅)4P⁽¹⁺⁾=[Fe(CH₃Si(C₆H₃(S)(Si(CH₃)3))3)(C₄H₈O)][(C₆H₅)4P]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Fe(CH₃Si(C₆H₃(Si(CH₃)3)S)3)(C₄H₈O)^(1-)*(C₆H₅)4P⁽¹⁺⁾=[Fe(CH₃Si(C₆H₃(S)(Si(CH₃)3))3)(C₄H₈O)][(C₆H₅)4P]

There total 1 articles about Fe(CH₃Si(C₆H₃(Si(CH₃)3)S)3)(C₄H₈O)^(1-)*(C₆H₅)4P⁽¹⁺⁾=[Fe(CH₃Si(C₆H₃(S)(Si(CH₃)3))3)(C₄H₈O)][(C₆H₅)4P] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + iron(II) trifluoromethanesulfonate acetonitrile disolvate + (((CH3)3Si)(SH)C6H3)3SiCH3 (695203-00-0) + tetraphenylphosphonium bromide (2751-90-8) → Fe(CH3Si(C6H3(Si(CH3)3)S)3)(C4H8O)(1-)*(C6H5)4P(1+)=[Fe(CH3Si(C6H3(S)(Si(CH3)3))3)(C4H8O)][(C6H5)4P] (695202-95-0)

Guidance literature:

In tetrahydrofuran; acetonitrile; soln. of Li-comp. in THF added to Fe-comp., stirred at room temp. for 15min, soln. of PPh4Br in CH3CN added; solv. removed in vacuo, recrystn. from THF/Et2O; elem. anal.;

DOI:10.1002/anie.200352916

Reference yield: 82.0%

Fe(CH3Si(C6H3(Si(CH3)3)S)3)(C4H8O)(1-)*(C6H5)4P(1+)=[Fe(CH3Si(C6H3(S)(Si(CH3)3))3)(C4H8O)][(C6H5)4P] (695202-95-0) + carbon monoxide (201230-82-2) → Fe(CH3Si(C6H3(Si(CH3)3)S)3)(CO)3(1-)*(C6H5)4P(1+)=[Fe(CH3Si(C6H3(S)(Si(CH3)3))3)(CO)3][(C6H5)4P] (695202-97-2)

Guidance literature:

In tetrahydrofuran; soln. of Fe-comp. in THF treated with CO (1 atm) at -48°C for 1 h; concd., layered with Et2O at -48°C; elem. anal.;

DOI:10.1002/anie.200352916

upstream raw materials:

tetrahydrofuran

(((CH₃)3Si)(SH)C₆H₃)3SiCH₃

tetraphenylphosphonium bromide

Downstream raw materials:

Fe(CH₃Si(C₆H₃(Si(CH₃)3)S)3)(CO)3^(1-)*(C₆H₅)4P⁽¹⁺⁾=[Fe(CH₃Si(C₆H₃(S)(Si(CH₃)3))3)(CO)3][(C₆H₅)4P]