[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane

Base Information

Chemical Name:[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane
CAS No.:313973-95-4
Molecular Formula:C₃₀H₂₄BiF₆NO
Molecular Weight:737.497
Hs Code.:

Synonyms:[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane

Suppliers and Price of [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 1 raw suppliers

Chemical Property of [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane

There total 2 articles about [(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 22227-26-5
3,5-Bis(trifluoromethyl)benzamide

: 6729-60-8
tris(2-methylphenyl)bismuth dichloride

: 313973-95-4
[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane

Guidance literature:: With KOC(CH₃)3; In dichloromethane; under Ar; KOC(CH3)3 was added to a mixt. of the triarylbismuth dichloride, the amide and CH2Cl2 at -50°C, the mixt. was allowed to warm gradually to 25°C with stirring; the insol. solid was filtered through Celite, the filtrate was concd. under vac., the oily residue was crystd. from CH2Cl2/hexane;
DOI:10.1021/ja003623l

Reference yield:

: 233257-02-8
[(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane

: 313973-95-4
[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane

Guidance literature:: Multi-step reaction with 2 steps

1: water; dichloromethane

2: KOC(CH₃)3 / dichloromethane

With KOC(CH₃)3; In dichloromethane; water;
DOI:10.1021/ja003623l

Reference yield: 83.0%

: 313973-95-4
[(3,5-bis(trifluoromethyl)benzoyl)imino]tris(2-methylphenyl)-λ5-bismuthane

: 10050-08-5
tri-o-tolylbismuth

Guidance literature:: With (C(C₆H₅)2(OH))2; In dichloromethane; byproducts: (C6H5)2CO, H2NCOC6H3(CF3)2; under Ar; a mixt. of the bismuthane, 1,1,2,2-tetraphenylethanediol and CH2Cl2 was stirred at 25°C for 24 h; the solvent was evapd. under vac., the oily residue was chromd. on silica gel (hexane/CH3CH2O2CCH3);
DOI:10.1021/ja003623l