Tri-o-tolylbismuthine

Base Information

• Chemical Name: Tri-o-tolylbismuthine
• CAS No.: 10050-08-5
• Molecular Formula: C21H21 Bi
• Molecular Weight: 482.378
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID70450290
• Mol file: 10050-08-5.mol

Synonyms:Tri-o-tolylbismuthine;10050-08-5;Tris(2-methylphenyl)bismuthane;Tris(2-methylphenyl)bismuthine;tri-o-tolylbismuth;Bismuthine, tris(2-methylphenyl)-;trio-tolylbismuthine;DTXSID70450290;DWIMJCTYUMGECA-UHFFFAOYSA-N;MFCD00123270;AKOS015840503;AS-61346;FT-0757242;T1970;D92555

Chemical Property of Tri-o-tolylbismuthine

Chemical Property:

• Melting Point: 131.0 to 135.0 °C
• PSA: 0.00000
• LogP: 5.38560
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 482.14472
• Heavy Atom Count: 22
• Complexity: 287

Purity/Quality:

98% ^*data from raw suppliers

Tri-o-tolylbismuthine >98.0%(HPLC)(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=CC=C1[Bi](C2=CC=CC=C2C)C3=CC=CC=C3C

Technology Process of Tri-o-tolylbismuthine

There total 34 articles about Tri-o-tolylbismuthine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

thiophenol (108-98-5) + [(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane (233257-02-8) → tri-o-tolylbismuth (10050-08-5) + diphenyldisulfane (882-33-7)

Guidance literature:

In benzene; room temp., 3 h;

DOI:10.1021/om990252c

Reference yield: 100.0%

[(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane (233257-02-8) → tri-o-tolylbismuth (10050-08-5)

Guidance literature:

With C₆H₅SH; In benzene; byproducts: C6H5SSC6H5, H2NCOCF3; under Ar; a mixt. of the bismuthane, benzenethiol and benzene was stirred at 25°C for 3 h; the solvent was evapd. under vac., the oily residue was chromd. on silica gel (hexane/CH3CH2O2CCH3);

DOI:10.1021/ja003623l

Reference yield: 99.0%

[(trichloroacetyl)imino]tris(2-methylphenyl)-λ5-bismuthane (233257-03-9) → tri-o-tolylbismuth (10050-08-5)

Guidance literature:

With triphenylarsane; In benzene-d6; byproducts: (C6H5)3AsNCOCCl3; under Ar; a mixt. of the bismuthane, triphenylarsane and C6D6 was heatedat 60°C for 7 h;

DOI:10.1021/ja003623l

upstream raw materials:

2-methylphenyl bromide

ethanol

hydrazine hydrate

bismuth

Downstream raw materials:

tris(2-methylphenyl)bismuth dichloride

tri-o-tolylbismuth dibromide

bis(2-methylphenyl)bismuthinic acid

toluene