[(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane

Base Information

• Chemical Name: [(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane
• CAS No.: 233257-02-8
• Molecular Formula: C₂₃H₂₁BiF₃NO
• Molecular Weight: 593.401
• Mol file: 233257-02-8.mol

Synonyms:[(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane

Chemical Property of [(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane

There total 1 articles about [(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

2,2,2-trifluoroacetamide (354-38-1) + tris(2-methylphenyl)bismuth dichloride (6729-60-8) → [(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane (233257-02-8)

Guidance literature:

With KO(t)Bu; In dichloromethane; addn. of 2 equiv. KO(t)Bu to equimolar mixt. of Bi-compd. and amide at -50°C, warming to 10°C with stirring; filtration (Celite), concn. (reduced pressure), crystn. (CH2Cl2/hexane);elem. anal.;

DOI:10.1021/om990252c

Reference yield: 100.0%

thiophenol (108-98-5) + [(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane (233257-02-8) → tri-o-tolylbismuth (10050-08-5) + diphenyldisulfane (882-33-7)

Guidance literature:

In benzene; room temp., 3 h;

DOI:10.1021/om990252c

Reference yield: 100.0%

[(trifluoroacetyl)imino]tris-(2-methylphenyl)-λ(5)-bismuthane (233257-02-8) → tri-o-tolylbismuth (10050-08-5)

Guidance literature:

With C₆H₅SH; In benzene; byproducts: C6H5SSC6H5, H2NCOCF3; under Ar; a mixt. of the bismuthane, benzenethiol and benzene was stirred at 25°C for 3 h; the solvent was evapd. under vac., the oily residue was chromd. on silica gel (hexane/CH3CH2O2CCH3);

DOI:10.1021/ja003623l

upstream raw materials:

2,2,2-trifluoroacetamide

tris(2-methylphenyl)bismuth dichloride

Downstream raw materials:

2,2,2-trifluoro-N-o-tolylacetamide

tri-o-tolylbismuth

2,2,2-trifluoroacetamide

tris(2-methylphenyl)bismuth dichloride