NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5⁽³⁺⁾*3BF₄^(1-)=NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5(BF₄)3

Base Information

• Chemical Name: NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5⁽³⁺⁾*3BF₄^(1-)=NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5(BF₄)3
• CAS No.: 81688-54-2
• Molecular Formula: 3BF₄*C₁₅H₃₇CoN₇O₃
• Molecular Weight: 682.911

Synonyms:NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5⁽³⁺⁾*3BF₄^(1-)=NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5(BF₄)3

Chemical Property of NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5⁽³⁺⁾*3BF₄^(1-)=NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5(BF₄)3

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Technology Process of NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5⁽³⁺⁾*3BF₄^(1-)=NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5(BF₄)3

There total 1 articles about NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5⁽³⁺⁾*3BF₄^(1-)=NH₃CHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5(BF₄)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

Co(NH3)5(COOHCHNH2CH2CH(CH3)2)(3+)*3BF4(1-)*2H2O=Co(NH3)5(COOHCHNH2CH2CH(CH3)2)(BF4)3*2H2O (81688-38-2) + L-Phe-Leu (3303-55-7) + dicyclohexyl-carbodiimide (538-75-0) → NH3CHCH2C6H5CONHCHCOOCH2CH(CH3)2Co(NH3)5(3+)*3BF4(1-)=NH3CHCH2C6H5CONHCHCOOCH2CH(CH3)2Co(NH3)5(BF4)3 (81688-54-2)

Guidance literature:

With benzotriazol-1-ol; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; In dichloromethane; N,N-dimethyl-formamide; to soln. of Boc-L-Phe in CH2Cl2 at 0°C were added soln. of HOBT in DMF at 0°C and soln. of DCC in CH2Cl2 at 0°C, continuedfor 1 h at 0°C, then for 1 h at room temp., filtered, evapd. to dryness, DMF and Co-complex were added; diisopropylethylamine was added, stirred for 25 min at room temp., evapd., treated with ether, mixt. was stirred in CH2Cl2 and CF3COOH for 75 min at room temp., evapd., dissolved in H2O, purified by ion exchange column;

DOI:10.1021/ja00378a021

Reference yield:

BOC-glycine (4530-20-5) + NH3CHCH2C6H5CONHCHCOOCH2CH(CH3)2Co(NH3)5(3+)*3BF4(1-)=NH3CHCH2C6H5CONHCHCOOCH2CH(CH3)2Co(NH3)5(BF4)3 (81688-54-2) + dicyclohexyl-carbodiimide (538-75-0) + trifluoroacetic acid (76-05-1) → NH3CH2CONHCHCH2C6H5CONHCHCOOCH2CH(CH3)2Co(NH3)5(3+)*3CF3COO(1-)=NH3CH2CONHCHCH2C6H5CONHCHCOOCH2CH(CH3)2Co(NH3)5(CF3COO)3 (81688-57-5)

Guidance literature:

With 4-methyl-morpholine; In dichloromethane; byproducts: DCU; Boc-Gly was dissolved in CH2Cl2, cooled to 0°C, DCC in CH2Cl2 at0°C was added, stirred for 2 h at 0°C, filtered, filtratewas evapd. to dryness, solid was dissolved in DMF, Co-complex was added, stirred, N-methylmorpholine was adde; reaction was left for 20 min, concd., soln. was stirred with CF3COOH for 1 h at room temp., evapd. to dryness by rotary evaporator, dissolved in EtAc, extd. with aq. HOAc, purified by column chromy., eluted with CF3COOH, evapd. to dryness at room temp.;

DOI:10.1021/ja00378a021

upstream raw materials:

Co(NH₃)5(COOHCHNH₂CH₂CH(CH₃)2)⁽³⁺⁾*3BF₄^(1-)*2H₂O=Co(NH₃)5(COOHCHNH₂CH₂CH(CH₃)2)(BF₄)3*2H₂O

L-Phe-Leu

dicyclohexyl-carbodiimide

Downstream raw materials:

NH₃CH₂CONHCHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5⁽³⁺⁾*3CF₃COO^(1-)=NH₃CH₂CONHCHCH₂C₆H₅CONHCHCOOCH₂CH(CH₃)2Co(NH₃)5(CF₃COO)3

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