5-phenylacenaphthene

Base Information

• Chemical Name: 5-phenylacenaphthene
• CAS No.: 56252-14-3
• Molecular Formula: C₁₈H₁₄
• Molecular Weight: 230.309
• Mol file: 56252-14-3.mol

Synonyms:5-phenylacenaphthene

Chemical Property of 5-phenylacenaphthene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5-phenylacenaphthene

There total 3 articles about 5-phenylacenaphthene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

5-bromoacenaphthene (2051-98-1) + phenylmagnesium bromide (100-58-3) → 5-phenylacenaphthene (56252-14-3)

Guidance literature:

With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In diethyl ether; for 4h; Heating;

DOI:10.1002/(SICI)1099-0690(199903)1999:3<597::AID-EJOC597>3.0.CO;2-#

Reference yield:

5-bromoacenaphthene (2051-98-1) + phenylboronic acid (98-80-6) → 5-phenylacenaphthene (56252-14-3)

Guidance literature:

With potassium carbonate; In methanol; N,N-dimethyl-formamide; at 100 ℃; for 1.5h; Catalytic behavior; Microwave irradiation; Inert atmosphere;

DOI:10.1021/jacs.8b13397

Reference yield:

5-iodoacenaphthene (6861-64-9) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 5-phenylacenaphthene (56252-14-3)

Guidance literature:

Irradiation;

upstream raw materials:

5-iodoacenaphthene

benzene

5-bromoacenaphthene

phenylmagnesium bromide

Downstream raw materials:

3-phenylacenaphtho<1,2-a>acenaphthylene

5-phenylacenaphthylene

Refernces

• 1、 Bhattacharya, Saurav,Ayass, Wassim W.,Taffa, Dereje H.,Schneemann, Andreas,Semrau, A. Lisa,Wannapaiboon, Suttipong,Altmann, Philipp J.,P?thig, Alexander,Nisar, Talha,Balster, Torsten,Burtch, Nicholas C.,Wagner, Veit,Fischer, Roland A.,Wark, Michael,Kortz, Ulrich. "Discovery of Polyoxo-Noble-Metalate-Based Metal-Organic Frameworks". . p. 3385 - 3389. Retrieved 2019.