(1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

Base Information

Chemical Name:(1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol
CAS No.:99946-18-6
Molecular Formula:C₁₈H₂₃ClO₄S₂
Molecular Weight:402.963
Hs Code.:

Synonyms:(1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

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Chemical Property of (1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

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Technology Process of (1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

There total 4 articles about (1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 99908-18-6
(1S,2R,4R)-1-[(Z)-2-(4-Chloro-benzenesulfonyl)-vinylsulfanylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

: 99946-18-6
(1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

: 99894-22-1
(1S,2R,4R)-1-[(R)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In methanol; at -20 ℃;
DOI:10.1021/jo00359a014

Reference yield:

: 32501-91-0
((p-chlorophenyl)sulfonyl)acetylene

: 99946-18-6
(1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 62 percent / morpholine / acetonitrile / 18 h / Ambient temperature

2: m-chloroperoxybenzoic acid / CH₂Cl₂ / 0 °C

With morpholine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetonitrile;
DOI:10.1021/jo00359a014

Reference yield:

: 21286-54-4
Camphorsulfonyl chloride

: 99946-18-6
(1S,2R,4R)-1-[(S)-(Z)-2-(4-Chloro-benzenesulfonyl)-ethenesulfinylmethyl]-7,7-dimethyl-bicyclo[2.2.1]heptan-2-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 67 percent / LiAlH₄ / diethyl ether / 1.) RT, 2.) reflux

2: 62 percent / morpholine / acetonitrile / 18 h / Ambient temperature

3: m-chloroperoxybenzoic acid / CH₂Cl₂ / 0 °C

With morpholine; lithium aluminium tetrahydride; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane; acetonitrile;
DOI:10.1021/jo00359a014