{(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4

Base Information

Chemical Name:{(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4
CAS No.:94282-87-8
Molecular Formula:BF₄*C₃₄H₂₅ORu
Molecular Weight:637.447
Hs Code.:

Synonyms:{(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4

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Chemical Property of {(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4

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Technology Process of {(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4

There total 3 articles about {(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 14104-20-2
silver tetrafluoroborate

: bis[dicarbonylcyclopentadienylruthenium(I)]

: 501-65-5
diphenyl acetylene

: {CpRu(CO)3}BF₄

: Ru(CO)2(C₂(C₆H₅)2)(C₅H₅)⁽¹⁺⁾*BF₄^(1-)=Ru(CO)2(C₂(C₆H₅)2)(C₅H₅)BF₄

: 94282-87-8
{(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4

Guidance literature:: In dichloromethane; AgBF4 adding to a soln. of Ru complex and diphenylacetylene; identified by IR and NMR spectra;
DOI:10.1039/c39840001141

Reference yield:

: 94282-91-4
{(η5-cyclopentadienyl)Ru(NCMe)(η4-C4Ph4)}BF4

: 94282-87-8
{(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4

Guidance literature:: With CO; In dichloromethane; High Pressure; Ru-complex reacted with CO (10 atm, 50°C) in CH2Cl2;
DOI:10.1039/DT9870002803

Reference yield:

: 14104-20-2
silver tetrafluoroborate

: bis[dicarbonylcyclopentadienylruthenium(I)]

: 501-65-5
diphenyl acetylene

: Ru(CO)2(C₂(C₆H₅)2)(C₅H₅)⁽¹⁺⁾*BF₄^(1-)=Ru(CO)2(C₂(C₆H₅)2)(C₅H₅)BF₄

: 94282-87-8
{(η5-cyclopentadienyl)Ru(CO)(η4-C4Ph4)}BF4

Guidance literature:: In dichloromethane; byproducts: Ag; to a soln. of Ru-complex and PhCCPh in CH2Cl2 AgBF4 was added, the mixt. was stirred at room temp. overnight, filtered, washed with CH2Cl2 under N2; vol. of solvent was reduced in vac., Et2O was added, ppt. was washed with Et2O, dried in vac., the product was dissolved in H2O and NaBH4 was added to reduce (Ru(CO)3(Cp))BF4 if necessary (IR), extd. with CH2Cl2, crystd. from CH2Cl2-Et2O; elem. anal.;
DOI:10.1039/DT9870002803