N-trimethylsilyl-2-tert-butylmercaptoaniline

Base Information

Chemical Name:N-trimethylsilyl-2-tert-butylmercaptoaniline
CAS No.:884303-39-3
Molecular Formula:C₁₃H₂₃NSSi
Molecular Weight:253.484
Hs Code.:

Synonyms:N-trimethylsilyl-2-tert-butylmercaptoaniline

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-trimethylsilyl-2-tert-butylmercaptoaniline

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Technology Process of N-trimethylsilyl-2-tert-butylmercaptoaniline

There total 1 articles about N-trimethylsilyl-2-tert-butylmercaptoaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 75-77-4
chloro-trimethyl-silane

: 51942-41-7
o-aminophenyl tert-butyl sulfide

: 884303-39-3
N-trimethylsilyl-2-tert-butylmercaptoaniline

Guidance literature:: o-aminophenyl tert-butyl sulfide; With n-butyllithium; In diethyl ether; at 20 ℃; for 1h;

chloro-trimethyl-silane; In diethyl ether; at 0 - 20 ℃; for 1h;
DOI:10.1039/b514873a

Reference yield: 52.0%

: 884303-39-3
N-trimethylsilyl-2-tert-butylmercaptoaniline

: Mo(2,6-dimethylphenylimido)2Cl₂(1,2-dimethoxyethane)

: [Mo(N-2,6-Me₂C₆H₃)2(N-trimethylsilyl-2-tert-butylmercaptoaniline(-1H))Cl]

Guidance literature:: With n-BuLi; In tetrahydrofuran; byproducts: LiCl; under N2; soln. of n-BuLi (1 equiv.) added slowly to precooled soln. of ligand in THF; warmed to room temp.; stirred for 30 min; added dropwise to cold (-20°C) soln. of Mo complex (1 equiv.) in THF; stirred atroom temp. for 4 h; solvent removed in vac.; extd. with toluene; soln. filtered over Celite;concd.; crystd. at -30°C; filtered; crystals washed with hexane; dried in vac.; elem. anal.;
DOI:10.1039/b514873a

Reference yield:

: 884303-39-3
N-trimethylsilyl-2-tert-butylmercaptoaniline

: 13637-68-8
dioxomolybdenum(VI) dichloride

: Mo(NC₆H₄SC(CH₃)3)2(OSi(CH₃)3)2

: bis(N-trimethylsilyl-2-tert-butylmercaptoaniline(-1H))dioxomolybdenum(VI)

: [Mo(N-2-t-BuSC₆H₄)2(N-trimethylsilyl-2-tert-butylmercaptoaniline(-1H))(OSiMe₃)]

Guidance literature:: With n-BuLi; In tetrahydrofuran-d8; benzene-d6; under N2; soln. of n-BuLi (1 equiv.) added slowly to precooled soln. of ligand in THF; warmed to room temp.; stirred for 30 min; added dropwise to soln. of MoO2Cl2 (0.5 equiv.) in THF; stirred at room temp. for 4 h; solvent removed in vac.; extd. with toluene; soln. filtered over Celite;solvent removed; recrystd. from cold pentane (-35°C); mixt. of t hree Mo complexes obtained;
DOI:10.1039/b514873a