5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde

Base Information

Chemical Name:5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde
CAS No.:141665-47-6
Molecular Formula:C₁₂H₁₈O₃
Molecular Weight:210.273
Hs Code.:

Synonyms:5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde

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Chemical Property of 5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde

There total 1 articles about 5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 562-13-0
2,2-dimethyl-1,3-cyclohexanedione

: 141665-47-6
5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1.1: 88 percent / (+/-)-camphor-10-sulfonic acid / benzene / 0.5 h / Heating

2.1: LiHMDS / hexane; tetrahydrofuran / 1 h / -78 °C

2.2: 89 percent / hexane; tetrahydrofuran / 3.5 h / -78 - 20 °C

3.1: hydrazine hydrate; triethylamine / ethanol / 312 h / Heating

4.1: 9.2 g / DBN; I₂ / diethyl ether / 0.5 h / 20 °C

5.1: t-BuLi / pentane; tetrahydrofuran / 0.5 h / -78 °C

5.2: pentane; tetrahydrofuran / 1.67 h / -78 - 20 °C

With 2,6-dichloro-benzonitrile; camphor-10-sulfonic acid; iodine; tert.-butyl lithium; hydrazine hydrate; triethylamine; lithium hexamethyldisilazane; In tetrahydrofuran; diethyl ether; ethanol; hexane; pentane; benzene;
DOI:10.1016/S0040-4020(03)00699-9

Reference yield:

: 141665-47-6
5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde

: 595568-62-0
5-(tert-butyl-dimethyl-silanyloxymethyl)-4,6,6-trimethyl-cyclohexa-1,4-dienecarbaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1.1: CeCl₃*7H₂O; NaBH₄ / methanol / 0.5 h / 0 °C

2.1: 2.75 g / HCl / H₂O / 0.5 h / 20 °C

3.1: 92 percent / imidazole / CH₂Cl₂ / 14 h / 20 °C

4.1: 87 percent / CH₂Cl₂ / 16 h / 26 °C

5.1: n-BuLi / hexane; tetrahydrofuran / 1 h / -78 °C

5.2: hexane; tetrahydrofuran / 1.67 h / -78 - 20 °C

With 1H-imidazole; hydrogenchloride; sodium tetrahydroborate; n-butyllithium; cerium(III) chloride; In tetrahydrofuran; methanol; hexane; dichloromethane; water; 1.1: Luche reduction;
DOI:10.1016/S0040-4020(03)00699-9

Reference yield:

: 141665-47-6
5,5-(ethylenedioxy)-2,6,6-trimethyl-1-cyclohexenecarboxaldehyde

: 595568-54-0
2-(tert-butyldimethylsiloxymethyl)-4-hydroxymethyl-1,3,3-trimethyl-cyclohexa-1,4-diene

Guidance literature:: Multi-step reaction with 6 steps

1.1: CeCl₃*7H₂O; NaBH₄ / methanol / 0.5 h / 0 °C

2.1: 2.75 g / HCl / H₂O / 0.5 h / 20 °C

3.1: 92 percent / imidazole / CH₂Cl₂ / 14 h / 20 °C

4.1: 87 percent / CH₂Cl₂ / 16 h / 26 °C

5.1: n-BuLi / hexane; tetrahydrofuran / 1 h / -78 °C

5.2: hexane; tetrahydrofuran / 1.67 h / -78 - 20 °C

6.1: 718 mg / CeCl₃*7H₂O; NaBH₄ / methanol / 0.5 h / 0 °C

With 1H-imidazole; hydrogenchloride; sodium tetrahydroborate; n-butyllithium; cerium(III) chloride; In tetrahydrofuran; methanol; hexane; dichloromethane; water; 1.1: Luche reduction / 6.1: Luche reduction;
DOI:10.1016/S0040-4020(03)00699-9