(μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

Base Information

Chemical Name:(μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl
CAS No.:1187468-93-4
Molecular Formula:C₁₈H₁₄Co₂O₉
Molecular Weight:492.29
Hs Code.:

Synonyms:(μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

Suppliers and Price of (μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

There total 1 articles about (μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.8%

: 67-56-1
methanol

: 1187468-91-2
[HCCCH(OH)C₆H₃(OCH₃)2]Co₂(CO)6

: 1187468-93-4
(μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

Guidance literature:: With HBF₄*(CH₃)2O; In methanol; diethyl ether; (N2); Schlenk technique; soln. of acid added dropwise over 5 min to soln. of Co complex in ether at -20°C; stirred for 1 h; ethereal layer removed; washed (ether, -20°C); ether added at -20°C; MeOH added; stirred (20°C, 0.5 h; dild. with H2O; org. layer washed (H2O); dried (Na2SO4); evapd. (vac.); elem. anal.;
DOI:10.1021/om900448j

Reference yield: 80.0%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 1187468-93-4
(μ-η2-3-methoxy-3-(3',4'-dimethoxyphenyl)-1-propyne)dicobalt hexacarbonyl

: meso-(μ-η2-3,4-di(3',4'-dimethoxyphenyl)-1,5-hexadiyne)bis(dicobalthexacarbonyl)

: d,l-(μ-η2-3,4-di(3',4'-dimethoxyphenyl)-1,5-hexadiyne)bis(dicobalthexacarbonyl)

Guidance literature:: With trifluoromethylsulfonic anhydride; In 1,2-dichloro-ethane; (N2); Schlenk technique; anhydride added dropwise to Co complex/C2H4Cl2 (-20°C); stirred (-20°C, 10 min; 20°C, 10 min); refluxed (83°C, 3 min); cooled (20°C); MeOH added; stirred (30 min); Co2(CO)8 added; stirred (2 h; dild. with H2O; extd. (ether); org. layer washed (H2O); dried (Na2SO4); evapd. (vac.); fractionally chromd. (silica gel, petroleum ether/ether, 1/2); elem. anal.;
DOI:10.1021/om900448j