2-Acetylphenylboronic acid

Base Information

Chemical Name:2-Acetylphenylboronic acid
CAS No.:308103-40-4
Molecular Formula:C8H9BO3
Molecular Weight:163.969
Hs Code.:29310095
DSSTox Substance ID:DTXSID50370200
Nikkaji Number:J1.983.808K
Wikidata:Q72435655
Mol file:308103-40-4.mol

Synonyms:2-acetylphenylboronic acid

Suppliers and Price of 2-Acetylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-Acetylphenylboronic acid
25g
$ 2520.00

SynQuest Laboratories
2-Acetylbenzeneboronic acid
1 g
$ 112.00

Sigma-Aldrich
2-Acetylphenylboronic acid
5g
$ 114.00

Sigma-Aldrich
2-Acetylphenylboronic acid
25g
$ 511.00

Crysdot
2-Acetylphenylboronic acid 97%
5g
$ 204.00

Apolloscientific
2-Acetylbenzeneboronicacid 95+%
25g
$ 728.00

Apolloscientific
2-Acetylbenzeneboronicacid 95+%
5g
$ 188.00

Apolloscientific
2-Acetylbenzeneboronicacid 95+%
1g
$ 95.00

AOBChem
2-Acetylphenylboronic acid 97%
5g
$ 94.00

AOBChem
2-Acetylphenylboronic acid 97%
10g
$ 160.00

Total 78 raw suppliers

Chemical Property of 2-Acetylphenylboronic acid

Chemical Property:

Appearance/Colour:white to light yellow crystal powder
Vapor Pressure:1.7E-05mmHg at 25°C
Melting Point:170 ºC (dec.)(lit.)
Refractive Index:1.535
Boiling Point:349.9 ºC at 760 mmHg
PKA:8.20±0.58(Predicted)
Flash Point:165.4 ºC
PSA：57.53000
Density:1.19 g/cm³
LogP:-0.43100
Storage Temp.:0-6°C
Water Solubility.:Slightly soluble in water.
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:164.0644743
Heavy Atom Count:12
Complexity:170

Purity/Quality:

99% ^*data from raw suppliers

2-Acetylphenylboronic acid ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi,C
Hazard Codes:Xi,C
Statements: 36/37/38
Safety Statements: 26-36-37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=CC=C1C(=O)C)(O)O
Uses 2-Acetylphenylboronic acid is a reactant used for a variety of coupling reactions, as well as synthesis and hydroxy masking, Suzuki-Miyaura cross-coupling reactions, rhodium-catalyzed annulation of ynamides, transient masking of hydroxy groups, cationic palladium complex-catalyzed diastereoselective tandem annulation, hydrogen peroxide mediated formation of heteroaryl ethers and copper-catalyzed transmetalation and homocoupling.

Technology Process of 2-Acetylphenylboronic acid

There total 16 articles about 2-Acetylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 325141-75-1
1-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)ethan-1-one

: 308103-40-4
(2-acetylphenyl)boronic acid

Guidance literature:: With polystyrene boronic acid; trifluoroacetic acid; In acetonitrile; for 18h; Heating;
DOI:10.1016/j.tetlet.2004.07.014

Reference yield: 90.0%

: 150-46-9
triethyl borate

: 2142-69-0
2-bromophenyl methyl ketone

: 308103-40-4
(2-acetylphenyl)boronic acid

Guidance literature:: 2-bromophenyl methyl ketone; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;

triethyl borate; In tetrahydrofuran; at 20 ℃; for 4h;

Reference yield:

: C₁₅H₁₆BNO₂

: 100-46-9
benzylamine

: 308103-40-4
(2-acetylphenyl)boronic acid

Guidance literature:: With tris(2-carboxyethyl)phosphine; water; In aq. phosphate buffer; water-d2; for 0.0833333h; Reagent/catalyst;
DOI:10.1016/j.tetlet.2017.06.069