(R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide

Base Information

Chemical Name:(R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide
CAS No.:446879-32-9
Molecular Formula:C₂₀H₂₁IO₃
Molecular Weight:436.289
Hs Code.:

Synonyms:(R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide

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Chemical Property of (R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide

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Technology Process of (R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide

There total 3 articles about (R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 3240-34-4
[bis(acetoxy)iodo]benzene

: 446879-30-7
(R)-methyl 3-oxo-6-phenylheptanoate

: 446879-32-9
(R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide

Guidance literature:: With potassium hydroxide; In methanol; at 0 ℃; for 0.166667h;
DOI:10.1002/1522-2675(200202)85:2<483::AID-HLCA483>3.0.CO;2-Q

Reference yield:

: 37778-99-7
(S)-2-phenyl-1-propanol

: 446879-32-9
(R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide

Guidance literature:: Multi-step reaction with 3 steps

1.1: 85 percent / Ph₃P; 1H-imidazole; I₂ / diethyl ether; acetonitrile / 3 h / 20 °C

2.1: BuLi; diisopropylamine / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 0.5 h / -25 - 0 °C

2.2: 54 percent / HMPA / tetrahydrofuran; hexane / 1 h / 20 °C

3.1: 76 percent / KOH / methanol / 0.17 h / 0 °C

With 1H-imidazole; potassium hydroxide; n-butyllithium; iodine; diisopropylamine; triphenylphosphine; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; acetonitrile;
DOI:10.1002/1522-2675(200202)85:2<483::AID-HLCA483>3.0.CO;2-Q

Reference yield:

: 446879-29-4
(S)-(2-iodo-1-methylethyl)benzene

: 446879-32-9
(R)-phenyliodonium 1-methoxy-1,3-dioxo-6-phenylheptylide

Guidance literature:: Multi-step reaction with 2 steps

1.1: BuLi; diisopropylamine / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 0.5 h / -25 - 0 °C

1.2: 54 percent / HMPA / tetrahydrofuran; hexane / 1 h / 20 °C

2.1: 76 percent / KOH / methanol / 0.17 h / 0 °C

With potassium hydroxide; n-butyllithium; diisopropylamine; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane;
DOI:10.1002/1522-2675(200202)85:2<483::AID-HLCA483>3.0.CO;2-Q