2-Chloro-4-methoxyphenylboronic acid

Base Information

Chemical Name:2-Chloro-4-methoxyphenylboronic acid
CAS No.:219735-99-6
Molecular Formula:C7H8BClO3
Molecular Weight:186.403
Hs Code.:29319090
European Community (EC) Number:678-372-4
DSSTox Substance ID:DTXSID30378380
Nikkaji Number:J3.152.124F
Wikidata:Q72453315
Mol file:219735-99-6.mol

Synonyms:2-Chloro-4-methoxyphenylboronic acid;219735-99-6;(2-chloro-4-methoxyphenyl)boronic acid;2-Chloro-4-methoxybenzeneboronic acid;MFCD03411935;2-chloro-4-methoxyphenylboronicacid;Boronic acid, (2-chloro-4-methoxyphenyl)-;2-Chloro-4-Methoxyphenyl-Boronic Acid;SCHEMBL41797;DTXSID30378380;LOCGPWGCRVKCFN-UHFFFAOYSA-N;CS-D1033;BBL103986;STL557796;2-chloro-4-methoxy-phenylboronic acid;AKOS004114040;AB14285;GS-6514;2-chloro-4-methoxy phenyl boronic acid;2-chloro-4-methoxy-phenyl boronic acid;SY019957;[2-chloro-4-(methyloxy)phenyl]boronic acid;A4711;AM20050333;C2386;FT-0601776;EN300-1696852;2-Chloro-4-methoxyphenylboronic acid, AldrichCPR;J-508757

Suppliers and Price of 2-Chloro-4-methoxyphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
2-Chloro-4-methoxyphenylboronic acid
1g
$ 360.00

TRC
2-Chloro-4-methoxyphenylboronic acid
100mg
$ 75.00

TRC
2-Chloro-4-methoxyphenylboronic acid
50mg
$ 60.00

TCI Chemical
2-Chloro-4-methoxyphenylboronic Acid (contains varying amounts of Anhydride)
5g
$ 145.00

TCI Chemical
2-Chloro-4-methoxyphenylboronic Acid (contains varying amounts of Anhydride)
1g
$ 49.00

Synthonix
2-Chloro-4-methoxyphenylboronic acid 97%
5g
$ 60.00

SynQuest Laboratories
2-Chloro-4-methoxybenzeneboronic acid 95%
25 g
$ 260.00

SynQuest Laboratories
2-Chloro-4-methoxybenzeneboronic acid 95%
1 g
$ 21.00

SynQuest Laboratories
2-Chloro-4-methoxybenzeneboronic acid 95%
5 g
$ 79.00

Sigma-Aldrich
2-Chloro-4-methoxyphenylboronic acid Aldrich
1g
$ 57.00

Total 71 raw suppliers

Chemical Property of 2-Chloro-4-methoxyphenylboronic acid

Chemical Property:

Vapor Pressure:2.34E-05mmHg at 25°C
Melting Point:190-196 ºC
Boiling Point:343.4 ºC at 760 mmHg
PKA:8.66±0.58(Predicted)
Flash Point:161.5 ºC
PSA：49.69000
Density:1.32 g/cm³
LogP:0.02840
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:186.0255020
Heavy Atom Count:12
Complexity:145

Purity/Quality:

99% ^*data from raw suppliers

2-Chloro-4-methoxyphenylboronic acid ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36/37/39-37/39-37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=C(C=C(C=C1)OC)Cl)(O)O
Uses suzuki reaction

Technology Process of 2-Chloro-4-methoxyphenylboronic acid

There total 3 articles about 2-Chloro-4-methoxyphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 219735-98-5
2-chloro-1-iodo-4-methoxybenzene

: 219735-99-6
2-chloro-4-methoxyphenylboronic acid

Guidance literature:: 2-chloro-1-iodo-4-methoxybenzene; With n-butyllithium; Triisopropyl borate; In tetrahydrofuran; at -90 - 20 ℃; for 6.25h;

With hydrogenchloride; In water; for 1h;

Reference yield:

: 5419-55-6
Triisopropyl borate

: 50638-46-5
4-bromo-3-chloroanisole

: 219735-99-6
2-chloro-4-methoxyphenylboronic acid

Guidance literature:: 4-bromo-3-chloroanisole; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h;

Triisopropyl borate; In tetrahydrofuran; hexane; at -78 ℃; for 2h;