2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate

Base Information

Chemical Name:2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate
CAS No.:1403588-51-1
Molecular Formula:CF₃O₃S*C₁₇H₁₉N₂O
Molecular Weight:416.421
Hs Code.:

Synonyms:2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate

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Technology Process of 2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate

There total 2 articles about 2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 19556-22-0
2-(methoxy(phenyl)methyl)-1-methyl-1H-benzo[d]imidazole

: 333-27-7
methyl trifluoromethanesulfonate

: 1403588-51-1
2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate

Guidance literature:: In diethyl ether; at 20 ℃; for 15h; Inert atmosphere;
DOI:10.1002/anie.201204524

Reference yield:

: 100-52-7
benzaldehyde

: 1403588-51-1
2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.75 h / -78 °C / Inert atmosphere

1.2: 3 h / -78 - 0 °C / Inert atmosphere

2.1: sodium hydride / tetrahydrofuran / 0.5 h / -50 °C / Inert atmosphere

2.2: 2.5 h / -50 - 20 °C / Inert atmosphere

3.1: diethyl ether / 15 h / 20 °C / Inert atmosphere

With n-butyllithium; sodium hydride; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1002/anie.201204524

Reference yield: 98.0%

: 1403588-51-1
2-(methoxy(phenyl)methyl)-1,3-dimethyl-1H-benzo[d]imidazol-3-ium triflate

: 1403588-45-3
2-(methoxy(phenyl)methylene)-1,3-dimethyl-2,3-dihydro-1H-benzo[d]imidazole

Guidance literature:: With potassium tert-butylate; sodium hydride; In tetrahydrofuran; at 20 ℃; for 15h; Inert atmosphere; Darkness;
DOI:10.1002/anie.201204524