1,3-Bis(diphenylphosphino)propane nickel(II)chloride

Base Information

• Chemical Name: 1,3-Bis(diphenylphosphino)propane nickel(II)chloride
• CAS No.: 15629-92-2
• Molecular Formula: C27H26Cl2NiP2
• Molecular Weight: 542.04
• Hs Code.: 29319090
• Mol file: 15629-92-2.mol

Synonyms:1,3-Bis(diphenylphosphino)propane nickel(II)chloride;[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride;1,3-Bis(diphenylphosphino)propanenickel(II)chloride;Dichloro[1,3-bis(diphenylphosphino)propane]nickel(II);[1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride;AMY38504;AKOS016001699;B1313

Chemical Property of 1,3-Bis(diphenylphosphino)propane nickel(II)chloride

Chemical Property:

• Appearance/Colour: red to red-brown powder or crystals
• Vapor Pressure: 9E-11mmHg at 25°C
• Melting Point: 213 °C (dec.)(lit.)
• Boiling Point: 529.7 °C at 760 mmHg
• Flash Point: 291.5 °C
• PSA: 27.18000
• LogP: 7.02130
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 8
• Exact Mass: 540.024022
• Heavy Atom Count: 32
• Complexity: 350

Purity/Quality:

98%+ ^*data from raw suppliers

[1,3-Bis(diphenylphosphino)propane]nickel(II)Chloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,Xn
• Hazard Codes: T,Xn
• Statements: 49-36/37/38-42/43-40
• Safety Statements: 53-26-36/37/39-45-24-22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(CCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[Cl-].[Cl-].[Ni+2]
• Uses: suzuki reaction.Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation. Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

Technology Process of 1,3-Bis(diphenylphosphino)propane nickel(II)chloride

There total 4 articles about 1,3-Bis(diphenylphosphino)propane nickel(II)chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

nickel(II) chloride hexahydrate + 1,3-bis-(diphenylphosphino)propane (6737-42-4) → 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) (55659-61-5,15629-92-2,55659-60-4)

Guidance literature:

In methanol; isopropyl alcohol; at 60 ℃;

DOI:10.1080/00958972.2020.1837784

Reference yield:

1,3-bis-(diphenylphosphino)propane (6737-42-4) + nickel dichloride (83864-14-6) → 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) (55659-61-5,15629-92-2,55659-60-4)

Guidance literature:

In not given;

DOI:10.1021/ja0103492

Reference yield:

nickel(II) chloride hexahydrate → 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) (55659-61-5,15629-92-2,55659-60-4)

Guidance literature:

With DPPP; In ethanol; the warm soln. of Ni salt and ligand under inert gas; the soln. was filtered, ppt. was washed with heptane, ether, dried in vac.;

upstream raw materials:

1,3-bis-(diphenylphosphino)propane

nickel dichloride

Downstream raw materials:

2-(4-fluorophenylmethyl)thiophene

Ni(1,2-bis(diphenylphosphino)propane)(OSO₂CF₃)2

bis(1,3-bis(diphenylphosphino)propane)nickel⁽⁰⁾

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

Refernces

• 1、 Gu, Xiao-Li,Li, Jian-Rong,Li, Qian-Li,Guo, Yang,Jing, Xing-Bin,Chen, Zi-Bing,Zhao, Pei-Hua. "Mononuclear nickel(II) dithiolate complexes with chelating diphosphines: Insight into protonation and electrochemical proton reduction". . . Retrieved 2021/04/06.
• 2、 -. "METHOD FOR PRODUCING SULFONYL CHLORIDE COMPOUND". Page/Page column 8. . Retrieved 2008/12/06.