Technology Process of methyl 2-((1Z,3E)-4-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)buta-1,3-dien-1-yl)benzoate
There total 4 articles about methyl 2-((1Z,3E)-4-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)buta-1,3-dien-1-yl)benzoate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
silver(I) acetate; palladium diacetate; tris-(o-tolyl)phosphine;
In
acetonitrile;
at 50 ℃;
for 48h;
Inert atmosphere;
DOI:10.1039/c0ob00977f
- Guidance literature:
-
Multi-step reaction with 2 steps
1: Iodine monochloride / dichloromethane / -78 - 20 °C / Inert atmosphere
2: silver(I) acetate; palladium diacetate; tris-(o-tolyl)phosphine / acetonitrile / 48 h / 50 °C / Inert atmosphere
With
silver(I) acetate; palladium diacetate; Iodine monochloride; tris-(o-tolyl)phosphine;
In
dichloromethane; acetonitrile;
2: Heck-Mizoroki type reaction;
DOI:10.1039/c0ob00977f
- Guidance literature:
-
Multi-step reaction with 4 steps
1: sulfuric acid / Reflux
2: silver(I) acetate; palladium diacetate; triphenylphosphine / acetonitrile / 2 h / 70 °C / Inert atmosphere
3: Iodine monochloride / dichloromethane / -78 - 20 °C / Inert atmosphere
4: silver(I) acetate; palladium diacetate; tris-(o-tolyl)phosphine / acetonitrile / 48 h / 50 °C / Inert atmosphere
With
sulfuric acid; silver(I) acetate; palladium diacetate; Iodine monochloride; triphenylphosphine; tris-(o-tolyl)phosphine;
In
dichloromethane; acetonitrile;
2: Heck-Mizoroki type reaction / 4: Heck-Mizoroki type reaction;
DOI:10.1039/c0ob00977f
