methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate

Base Information

Chemical Name:methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate
CAS No.:1287212-32-1
Molecular Formula:C₁₆H₂₁BO₄
Molecular Weight:288.151
Hs Code.:

Synonyms:methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate

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Technology Process of methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate

There total 2 articles about methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 610-97-9
o-iodo-methyl-benzoic acid

: 4627-10-5
4,4,6-trimethyl-2-vinyl-1,3,2-dioxaborinane

: 1287212-32-1
methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate

Guidance literature:: With silver(I) acetate; palladium diacetate; triphenylphosphine; In acetonitrile; at 70 ℃; for 2h; Inert atmosphere;
DOI:10.1039/c0ob00977f

Reference yield:

: 609-67-6
2-Iodobenzoyl chloride

: 1287212-32-1
methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: sulfuric acid / Reflux

2: silver(I) acetate; palladium diacetate; triphenylphosphine / acetonitrile / 2 h / 70 °C / Inert atmosphere

With sulfuric acid; silver(I) acetate; palladium diacetate; triphenylphosphine; In acetonitrile; 2: Heck-Mizoroki type reaction;
DOI:10.1039/c0ob00977f

Reference yield: 93.0%

: 1287212-32-1
methyl 2-((E)-2-(4,4,6-trimethyl-1,3,2-dioxaborinan-2-yl)vinyl)benzoate

: C₁₀H₉ClO₂

: 1287212-33-2,886986-52-3
methyl 2-((Z)-2-iodovinyl)benzoate

Guidance literature:: With Iodine monochloride; In dichloromethane; at -78 - 20 ℃; optical yield given as %de; stereoselective reaction; Inert atmosphere;
DOI:10.1039/c0ob00977f