1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeurelacton

Base Information

Chemical Name:1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeurelacton
CAS No.:77301-67-8
Molecular Formula:C₁₂H₁₁ClO₂
Molecular Weight:222.671
Hs Code.:

Synonyms:1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeurelacton

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeurelacton

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Technology Process of 1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeurelacton

There total 4 articles about 1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeurelacton which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 94559-06-5,94596-48-2,94596-49-3,94596-50-6
1-Chlor-c-2-methyl-c-3-phenyl-t-2-(tetrahydro-2-pyranyloxymethyl)-r-1-cyclopropancarbonsaeure-methylester

: 77301-67-8,77341-61-8
1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeure-lacton

Guidance literature:: In tetrahydrofuran; water; acetic acid; for 8h; Ambient temperature;

Reference yield:

: 77301-64-5,77341-59-4,100163-46-0,100163-47-1
2,2-Dichlor-1-methyl-t-3-phenyl-r-1-cyclopropanmethanol-tetrahydro-2-pyranylether

: 77301-67-8,77341-61-8
1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeure-lacton

Guidance literature:: Multi-step reaction with 2 steps

1: BuLi, CO₂, dimethylsulfate / tetrahydrofuran; diethyl ether; petroleum ether; hexane / 1) -100 deg C - -90 deg C, 1h, 2) reflux, 4h

2: 92 percent / acetic acid; H₂O; tetrahydrofuran / 8 h / Ambient temperature

With n-butyllithium; carbon dioxide; dimethyl sulfate; In tetrahydrofuran; diethyl ether; hexane; water; acetic acid; Petroleum ether;

Reference yield:

: 124-38-9,18923-20-1
carbon dioxide

: 77301-64-5,77341-59-4,100163-46-0,100163-47-1
2,2-Dichlor-1-methyl-t-3-phenyl-r-1-cyclopropanmethanol-tetrahydro-2-pyranylether

: 77301-67-8,77341-61-8
1-Chlor-2c-hydroxymethyl-2t-methyl-3c-phenyl-1r-cyclopropancarbonsaeure-lacton

: 77301-67-8
1-Chlor-c-2-(hydroxymethyl)-t-2-methyl-t-3-phenyl-r-1-cyclopropancarbonsaeurelacton

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction; 1) hexane, THF, benzine, -105 deg C, 1 h, 2) hexane, THF, benzine, r.t.;