4-Trimethylsilylphenylboronic acid

Base Information

Chemical Name:4-Trimethylsilylphenylboronic acid
CAS No.:17865-11-1
Molecular Formula:C9H15 B O2 Si
Molecular Weight:194.113
Hs Code.:29319090
European Community (EC) Number:672-616-3
DSSTox Substance ID:DTXSID60274326
Nikkaji Number:J1.707.632I
Wikidata:Q82003701
Mol file:17865-11-1.mol

Synonyms:17865-11-1;4-Trimethylsilylphenylboronic acid;4-(Trimethylsilyl)phenylboronic acid;(4-(Trimethylsilyl)phenyl)boronic acid;[4-(trimethylsilyl)phenyl]boronic acid;4-TRIMETHYLSILYLBENZENEBORONIC ACID;(4-trimethylsilylphenyl)boronic Acid;4-(TRIMETHYLSILYL)BENZENEBORONIC ACID;Boronic acid, [4-(trimethylsilyl)phenyl]-;MFCD00093348;Boronic acid, B-[4-(trimethylsilyl)phenyl]-;(4-(Trimethylsilyl)phenyl)boronicacid;SCHEMBL1103785;DTXSID60274326;4-trimethylsilyl-phenylboronic acid;4-(Trimethylsilyl)phenylboranic acid;4-Trimethylsilyl phenyl boronic acid;BBL100557;STL554351;4-(trimethylsilyl)phenyl boronic acid;AKOS004119222;AB03337;AM80888;CS-W001042;s20001;B-[4-(Trimethylsilyl)phenyl]boronic acid;DS-14798;SY031638;FT-0637615;T2664;EN300-714512;4-(Trimethylsilyl)phenylboronic acid, >=95.0%;A812387;J-011390;J-516027;Z1255486786;4-(Trimethylsilyl)phenylboronic acid (contains varying amounts of anhydride)

Suppliers and Price of 4-Trimethylsilylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
4-(Trimethylsilyl)phenylboronic acid
100mg
$ 60.00

TCI Chemical
4-(Trimethylsilyl)phenylboronic Acid (contains varying amounts of Anhydride)
5g
$ 282.00

TCI Chemical
4-(Trimethylsilyl)phenylboronic Acid (contains varying amounts of Anhydride)
1g
$ 81.00

Synthonix
4-(Trimethylsilyl)phenylboronic acid 97%+
5g
$ 230.00

Synthonix
4-(Trimethylsilyl)phenylboronic acid 97%+
1g
$ 80.00

Synthonix
4-(Trimethylsilyl)phenylboronic acid 97%+
25g
$ 980.00

SynQuest Laboratories
(4-(Trimethylsilyl)phenyl)boronic acid
10 g
$ 685.00

Sigma-Aldrich
4-(Trimethylsilyl)phenylboronic acid ≥95.0%
1g
$ 76.10

Sigma-Aldrich
4-(Trimethylsilyl)phenylboronic acid ≥95.0%
5g
$ 109.00

Matrix Scientific
4-Trimethylsilylphenylboronic acid 97+%
25g
$ 139.00

Total 71 raw suppliers

Chemical Property of 4-Trimethylsilylphenylboronic acid

Chemical Property:

Vapor Pressure:0.00074mmHg at 25°C
Melting Point:173-178 °C(lit.)
Boiling Point:294.4°Cat760mmHg
PKA:8.42±0.10(Predicted)
Flash Point:131.8°C
PSA：40.46000
Density:1.01g/cm³
LogP:-0.08840
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:194.0934364
Heavy Atom Count:13
Complexity:160

Purity/Quality:

98% ^*data from raw suppliers

4-(Trimethylsilyl)phenylboronic acid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=C(C=C1)[Si](C)(C)C)(O)O

Technology Process of 4-Trimethylsilylphenylboronic acid

There total 6 articles about 4-Trimethylsilylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 4-(trimethylsilyl)phenylboronic acid MIDA ester

: 17865-11-1
(4-(trimethylsilyl)phenyl)boronic acid

Guidance literature:: With sodium hydroxide; In tetrahydrofuran; water; at 23 ℃; for 0.166667h;
DOI:10.1021/ol102194c

Reference yield: 85.0%

: 6999-03-7
1-bromo-4-(trimethylsilyl)benzene

: 17865-11-1
(4-(trimethylsilyl)phenyl)boronic acid

Guidance literature:: 1-bromo-4-(trimethylsilyl)benzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1.5h; Inert atmosphere;

With Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃;

With water; In tetrahydrofuran; hexane; ethyl acetate;

Reference yield: 56.0%

: 75-77-4
chloro-trimethyl-silane

: 5419-55-6
Triisopropyl borate

: 106-37-6
1.4-dibromobenzene

: 17865-11-1
(4-(trimethylsilyl)phenyl)boronic acid

Guidance literature:: 1.4-dibromobenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h; Inert atmosphere;

chloro-trimethyl-silane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 0.333333h; Inert atmosphere;

Triisopropyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1002/anie.201800396