C₃₇H₅₃N₁₅O₁₀S

Base Information

Chemical Name:C₃₇H₅₃N₁₅O₁₀S
CAS No.:264626-97-3
Molecular Formula:C₃₇H₅₃N₁₅O₁₀S
Molecular Weight:899.988
Hs Code.:

C<sub>37</sub>H<sub>53</sub>N<sub>15</sub>O<sub>10</sub>S

Synonyms:C₃₇H₅₃N₁₅O₁₀S

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Chemical Property of C₃₇H₅₃N₁₅O₁₀S

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Technology Process of C₃₇H₅₃N₁₅O₁₀S

There total 15 articles about C₃₇H₅₃N₁₅O₁₀S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 264626-96-2
4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol

: 74-88-4
methyl iodide

: 264626-97-3
C₃₇H₅₃N₁₅O₁₀S

Guidance literature:: 4-azido-6-(4-azido-6-{4-azido-6-[4-azido-6-(4-azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-yloxy]-2-methyl-tetrahydro-pyran-3-yloxy}-2-methyl-tetrahydro-pyran-3-yloxy)-2-methyl-tetrahydro-pyran-3-ol; With sodium hydride; In N,N-dimethyl-formamide; for 0.0833333h;

methyl iodide; In N,N-dimethyl-formamide; for 0.333333h; Further stages.;
DOI:10.1021/ja992513f

Reference yield:

: 4-O-acetyl-3-azido-2,3,6-trideoxy-L-ribo-hexopyranose

: 264626-97-3
C₃₇H₅₃N₁₅O₁₀S

Guidance literature:: Multi-step reaction with 13 steps

1.1: pyridine; DMAP / 0.33 h / 20 °C

2.1: BF₃*Et₂O / CH₂Cl₂ / 0.33 h / 20 °C

3.1: K₂CO₃ / methanol / 2 h / 20 °C

4.1: pyridine / CH₂Cl₂ / 1 h

5.1: 18-crown-6 / dimethylformamide / 4 h

6.1: LiOH / methanol

7.1: Et₃N / CH₂Cl₂ / 0.33 h / -78 °C

8.1: mCPBA / CH₂Cl₂ / -42 °C

9.1: 21 percent / 2,6-di-tert-butyl-4-methylpyridine; 4 Angstroem molecular sieves; triflic anhydride / toluene; CH₂Cl₂ / 0.25 h / -78 °C

10.1: 95 percent / pyridinium hydrofluoride / tetrahydrofuran

11.1: 74 percent / triflic anhydride; 4 Angstroem molecular sieves / CH₂Cl₂; diethyl ether / 0.25 h / -78 °C

12.1: 90 percent / pyridinium hydrofluoride / tetrahydrofuran / 1 h

13.1: NaH / dimethylformamide / 0.08 h

13.2: 97 percent / dimethylformamide / 0.33 h

With pyridine; dmap; lithium hydroxide; 2,6-di-tert-butyl-4-methylpyridine; 18-crown-6 ether; trifluoromethylsulfonic anhydride; 4 A molecular sieve; boron trifluoride diethyl etherate; sodium hydride; potassium carbonate; pyridine hydrogenfluoride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene; 1.1: Acetylation / 2.1: Substitution / 3.1: Hydrolysis / 4.1: sulphonation / 5.1: Esterification / 6.1: Hydrolysis / 7.1: silylation / 8.1: Oxidation / 9.1: Condensation / 10.1: desilylation / 11.1: Condensation / 12.1: desilylation / 13.1: Metallation / 13.2: Methylation;
DOI:10.1021/ja992513f

Reference yield:

: 283170-20-7
(2S,3R,4S,6S)-4-Azido-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-ol

: 264626-97-3
C₃₇H₅₃N₁₅O₁₀S

Guidance literature:: Multi-step reaction with 10 steps

1.1: pyridine / CH₂Cl₂ / 1 h

2.1: 18-crown-6 / dimethylformamide / 4 h

3.1: LiOH / methanol

4.1: Et₃N / CH₂Cl₂ / 0.33 h / -78 °C

5.1: mCPBA / CH₂Cl₂ / -42 °C

6.1: 21 percent / 2,6-di-tert-butyl-4-methylpyridine; 4 Angstroem molecular sieves; triflic anhydride / toluene; CH₂Cl₂ / 0.25 h / -78 °C

7.1: 95 percent / pyridinium hydrofluoride / tetrahydrofuran

8.1: 74 percent / triflic anhydride; 4 Angstroem molecular sieves / CH₂Cl₂; diethyl ether / 0.25 h / -78 °C

9.1: 90 percent / pyridinium hydrofluoride / tetrahydrofuran / 1 h

10.1: NaH / dimethylformamide / 0.08 h

10.2: 97 percent / dimethylformamide / 0.33 h

With pyridine; lithium hydroxide; 2,6-di-tert-butyl-4-methylpyridine; 18-crown-6 ether; trifluoromethylsulfonic anhydride; 4 A molecular sieve; sodium hydride; pyridine hydrogenfluoride; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene; 1.1: sulphonation / 2.1: Esterification / 3.1: Hydrolysis / 4.1: silylation / 5.1: Oxidation / 6.1: Condensation / 7.1: desilylation / 8.1: Condensation / 9.1: desilylation / 10.1: Metallation / 10.2: Methylation;
DOI:10.1021/ja992513f