6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose

Base Information

Chemical Name:6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose
CAS No.:942622-24-4
Molecular Formula:C₄₄H₆₀O₂₄
Molecular Weight:972.946
Hs Code.:

Synonyms:6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose

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Chemical Property of 6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose

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Technology Process of 6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose

There total 15 articles about 6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 942622-18-6
3'-O-benzoyl-2,1':4,6-di-O-isopropylidene-3-O-methoxymethyl-4',6'-O-tetraisopropyldisiloxanilidene sucrose

: 942622-24-4
6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose

Guidance literature:: Multi-step reaction with 6 steps

1: 83 percent / hydrogen chloride; methanol / 2 h / 20 °C

2: 83 percent / pyridine / 0.5 h / 20 °C

3: 57 percent / N-iodosuccinimide; trimethylsilyl trifluoromethanesulfonate; MS 4 Angstroem / CH₂Cl₂ / 1 h / -40 °C

4: 98 percent / pyridine / 4 h / 20 °C

5: 71 percent / tetra-n-butylammonium nitrite / dimethylformamide / 12 h / 90 °C

6: 92 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 3 h

With pyridine; hydrogenchloride; methanol; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; MS 4 Angstroem; tetrabutyl ammonium fluoride; tetrabutylammonium nitrite; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2007.03.138

Reference yield:

: 3'-O-benzoyl-3-O-methoxymethyl-4',6'-O-tetraisopropyldisiloxanilidene sucrose

: 942622-24-4
6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose

Guidance literature:: Multi-step reaction with 5 steps

1: 83 percent / pyridine / 0.5 h / 20 °C

2: 57 percent / N-iodosuccinimide; trimethylsilyl trifluoromethanesulfonate; MS 4 Angstroem / CH₂Cl₂ / 1 h / -40 °C

3: 98 percent / pyridine / 4 h / 20 °C

4: 71 percent / tetra-n-butylammonium nitrite / dimethylformamide / 12 h / 90 °C

5: 92 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 3 h

With pyridine; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; MS 4 Angstroem; tetrabutyl ammonium fluoride; tetrabutylammonium nitrite; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2007.03.138

Reference yield:

: 942622-20-0
6,1'-di-O-acetyl-3'-O-benzoyl-3-O-methoxymethyl-4',6'-O-tetraisopropyldisiloxanilidene sucrose

: 942622-24-4
6,1'-di-O-acetyl-4,3'-di-O-benzoyl-3-O-methoxymethyl-2-O-(3,4,6-tri-O-methoxymethyl-β-D-glucopyranosyl) sucrose

Guidance literature:: Multi-step reaction with 4 steps

1: 57 percent / N-iodosuccinimide; trimethylsilyl trifluoromethanesulfonate; MS 4 Angstroem / CH₂Cl₂ / 1 h / -40 °C

2: 98 percent / pyridine / 4 h / 20 °C

3: 71 percent / tetra-n-butylammonium nitrite / dimethylformamide / 12 h / 90 °C

4: 92 percent / tetra-n-butylammonium fluoride / tetrahydrofuran / 3 h

With pyridine; N-iodo-succinimide; trimethylsilyl trifluoromethanesulfonate; MS 4 Angstroem; tetrabutyl ammonium fluoride; tetrabutylammonium nitrite; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2007.03.138