Dimethyl(3-phenylpropyl)silane

Base Information

• Chemical Name: Dimethyl(3-phenylpropyl)silane
• CAS No.: 18036-54-9
• Molecular Formula: C₁₁H₁₈Si
• Molecular Weight: 178.349
• European Community (EC) Number: 660-685-2
• Nikkaji Number: J3.465.259G
• Wikidata: Q82208773
• Mol file: 18036-54-9.mol

Synonyms:dimethyl(3-phenylpropyl)silane;AKOS024338726

Chemical Property of Dimethyl(3-phenylpropyl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 178.117777109
• Heavy Atom Count: 12
• Complexity: 104

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[SiH](C)CCCC1=CC=CC=C1

Technology Process of Dimethyl(3-phenylpropyl)silane

There total 3 articles about Dimethyl(3-phenylpropyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

allylbenzene (300-57-2,57807-91-7) + dimethylmethoxysilane (18033-75-5) → dimethyl(3-phenylpropyl)silane (18036-54-9)

Guidance literature:

With C₂₄H₃₀ClN₃NiO₂; sodium t-butanolate; In tetrahydrofuran; at 20 ℃; for 6h; Inert atmosphere; Glovebox;

DOI:10.1021/acs.orglett.6b00792

Reference yield:

dimethylmonochlorosilane (1066-35-9) + 3-phenylpropylmagnesium bromide (1462-75-5) → dimethyl(3-phenylpropyl)silane (18036-54-9)

Guidance literature:

DOI:10.1021/ja01469a033

Reference yield:

→ dimethyl(3-phenylpropyl)silane (18036-54-9)

Guidance literature:

(3-Phenylpropyl)-dimethylchlorsilan, LiAlH4 (Red.);

DOI:10.1016/S0040-4039(01)88003-5

upstream raw materials:

dimethylmonochlorosilane

3-phenylpropylmagnesium bromide

allylbenzene

dimethylmethoxysilane

Downstream raw materials:

1,1-Dimethyl-2-phenyl-1-silacyclobutane