1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide

Base Information

• Chemical Name: 1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide
• CAS No.: 1497423-69-4
• Molecular Formula: Br*C₁₂H₁₅N₂OS
• Molecular Weight: 315.234
• Mol file: 1497423-69-4.mol

Synonyms:1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide

Chemical Property of 1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide

Chemical Property:

Purity/Quality:

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Technology Process of 1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide

There total 1 articles about 1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

1-methyl-1H-imidazole (616-47-7) + 1-[(bromomethyl)-sulfinyl]-4-methylbenzene (26910-35-0) → 1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide (1497423-69-4)

Guidance literature:

With air; In acetonitrile; at 110 ℃; for 10h; Microwave irradiation; Sealed tube;

DOI:10.1021/om400981x

Reference yield: 95.0%

1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide (1497423-69-4) → bis{1-methyl-3-[(p-tolylsulfinyl)methyl]imidazol-2-ylidene}-silver(I) dibromoargentate

Guidance literature:

With silver(l) oxide; In acetonitrile; at 20 ℃; for 5h; Darkness;

DOI:10.1021/om400981x

Reference yield: 95.0%

1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide (1497423-69-4) → chloro{1-methyl-3-[(p-tolylsulfinyl)methyl]imidazol-2-ylidene}palladium(II)

Guidance literature:

1-methyl-3-[(p-tolylsulfinyl)methyl]-1H-imidazol-3-ium bromide; With silver(l) oxide; In acetonitrile; at 20 ℃; for 5h; Darkness;

With dichloro bis(acetonitrile) palladium(II); In acetonitrile; at 20 ℃; for 16h;

DOI:10.1021/om400981x

upstream raw materials:

1-methyl-1H-imidazole

1-[(bromomethyl)-sulfinyl]-4-methylbenzene