Technology Process of 2,5-bis(trichlorotin)-1,4-dioctyloxybenzene
There total 2 articles about 2,5-bis(trichlorotin)-1,4-dioctyloxybenzene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
not given;
byproducts: trimethyltin chloride; under N2; mixt. was warmed to 120°C under stirring for 4.5 h; excess SnCl4 and secondary products were evapd. under reduced pressure at 120°C; elem. anal.;
DOI:10.1021/om070078p
- Guidance literature:
-
Multi-step reaction with 2 steps
1: tert-butyllithium; aq. NH4Cl / diethyl ether; tetrahydrofuran; pentane
2: not given
With
tert-butyllithium; aq. NH4Cl;
In
tetrahydrofuran; diethyl ether; pentane;
DOI:10.1021/om070078p
- Guidance literature:
-
With
n-butyllithium;
In
hexane; toluene;
under N2; to soln. of propyne in toluene was added slowly n-BuLi in hexane at -78°C, after stirring for 2 h at room temp., soln. of trichlorotin comp. in toluene was added at -78°C, suspn. was stirred at room temp. for 12 h; suspn. was filtered on dry MgSO4, solvent was evapd.; elem. anal.;
DOI:10.1021/om070078p
