2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane

Base Information

• Chemical Name: 2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane
• CAS No.: 461051-83-2
• Molecular Formula: C₁₆H₂₆S₂Si
• Molecular Weight: 310.6
• Mol file: 461051-83-2.mol

Synonyms:2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane

Chemical Property of 2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane

There total 2 articles about 2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

2-Phenyl-[1,3]dithiane (5425-44-5) + t-butyldimethylsiyl triflate (69739-34-0) → 2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane (461051-83-2)

Guidance literature:

2-Phenyl-[1,3]dithiane; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.25h; Inert atmosphere;

t-butyldimethylsiyl triflate; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/chem.201704776

Reference yield: 91.0%

2-Phenyl-[1,3]dithiane (5425-44-5) + tert-butyldimethylsilyl chloride (18162-48-6) → 2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane (461051-83-2)

Guidance literature:

With n-butyllithium; In various solvent(s);

DOI:10.1021/ol0263649

Reference yield: 100.0%

2-phenyl-2-(tert-butyl dimethylsilyl)-1,3-dithiane (461051-83-2) → (tert-butyldimethylsilyl)(phenyl)methanone (132868-67-8)

Guidance literature:

With chloroamine-T; In methanol; water; acetone; for 0.25h; Ambient temperature;

DOI:10.1055/s-1992-26287

upstream raw materials:

2-Phenyl-[1,3]dithiane

t-butyldimethylsiyl triflate

tert-butyldimethylsilyl chloride

Downstream raw materials:

(tert-butyldimethylsilyl)(phenyl)methanone

1-(tert-butyldimethylsiloxy-phenyl-methoxy)-2,3,4,6-tetra-O-acetyl-α-D-galactopyranoside

1-(tert-butyldimethylsiloxy-phenyl-methoxy)-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

1-(tert-Butyl-dimethyl-silanyl)-2,2,3,3,4,4,5,5,6,6,7,7,7-tridecafluoro-1-phenyl-heptan-1-ol