((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*Li⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)Li

Base Information

Chemical Name:((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*Li⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)Li
CAS No.:88635-92-1
Molecular Formula:C₆₀H₄₅SnW*Li
Molecular Weight:1075.52
Hs Code.:

((C<sub>6</sub>H<sub>5</sub>)CC(C<sub>6</sub>H<sub>5</sub>))3WSn(C<sub>6</sub>H<sub>5</sub>)3<sup>(1-)</sup>*Li<sup>(1+)</sup> = (((C<sub>6</sub>H<sub>5</sub>)CC(C<sub>6</sub>H<sub>5</sub>))3WSn(C<sub>6</sub>H<sub>5</sub>)3)Li

Synonyms:((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*Li⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)Li

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Chemical Property of ((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*Li⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)Li

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Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of ((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*Li⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)Li

There total 1 articles about ((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*Li⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)Li which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 12120-72-8
tris(diphenylacetylene)tungsten monocarbonyl

: 639-58-7
triphenyltin chloride

: 88635-92-1
((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*Li⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)Li

Guidance literature:: With lithium naphthalide; In tetrahydrofuran; dropwise addn. of soln. of C10H7Li (2 equiv.; from C10H8 and 1.5 equiv. Li in THF) to stirred, cooled (-78.degee.C) soln. of W-complex, 5min stirred, dropwise addn. of cooled (-78°C) soln. of Ph3SnCl, warmed up to room temp., stirred 1h; solvent removed (vac.), residue washed with toluene, filtered, dried under vac., 3h, all reactions under N2; reaction monitored by IR;
DOI:10.1021/ja00320a020

Reference yield: 65.0%

: 88635-92-1
((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*Li⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)Li

: 71-91-0
tetraethylammonium bromide

: 88635-91-0
((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3^(1-)*N(C₂H₅)4⁽¹⁺⁾ = (((C₆H₅)CC(C₆H₅))3WSn(C₆H₅)3)(N(C₂H₅)4)

Guidance literature:: In ethanol; addn. of saturated soln. of anhydrous NEt4Br (2 equiv.) in EtOH to saturated soln. of W-complex in EtOH, ppt. filtered, under dry N2, minimized exposure to light; ppt. washed with water, dried under vac., 3h, recrystd. from acetone at -60°C (recrystd. from CH2Cl2/diethyl ether as CH2Cl2 solvate or from acetone/diethyl ether as diethyl ether solvate; elem. anal.;
DOI:10.1021/ja00320a020